Support and promoter effects in the selective oxidation of ethane to acetic acid catalyzed by Mo-V-Nb oxides
作者： Xuebing Li , Enrique Iglesia
DOI: 10.1016/J.APCATA.2007.10.021
关键词: Ethylene 、 Heterogeneous catalysis 、 Oxide 、 Catalysis 、 Carboxylic acid 、 Inorganic chemistry 、 Acetaldehyde 、 Chemistry 、 Acetic acid 、 Selectivity
摘要: … for practical acetic acid yields from ethane oxidation, and give low acetic acid productivities (… We find that dispersed VO x domains can activate ethane and convert it to acetic acid, while …
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berkeley.edu 参考文章(32)
M Dieterle, G Mestl, J Jäger, Y Uchida, H Hibst, R Schlögl, Mixed molybdenum oxide based partial oxidation catalyst: 2. Combined X-ray diffraction, electron microscopy and Raman investigation of the phase stability of (MoVW)5O14-type oxides Journal of Molecular Catalysis A-chemical. ,vol. 174, pp. 169- 185 ,(2001) , 10.1016/S1381-1169(01)00074-7
David Linke, Dorit Wolf, Manfred Baerns, Olaf Timpe, Robert Schlögl, Sabine Zeyβ, Uwe Dingerdissen, Catalytic partial oxidation of ethane to acetic acid over Mo1V0.25Nb0.12Pd0.0005Ox. I. Catalyst performance and reaction mechanism Journal of Catalysis. ,vol. 205, pp. 16- 31 ,(2002) , 10.1006/JCAT.2001.3367
J GALOWNIA, A WIGHT, A BLANC, J LABINGER, M DAVIS, Partially reduced heteropolyanions for the oxidative dehydrogenation of ethane to ethylene and acetic acid at atmospheric pressure Journal of Catalysis. ,vol. 236, pp. 356- 365 ,(2005) , 10.1016/J.JCAT.2005.10.010
J SEOANE, Ethylene oxidation to acetic acid with Pd-V2O5 catalysts: II. Kinetics of the catalytic reaction Journal of Catalysis. ,vol. 63, pp. 191- 200 ,(1980) , 10.1016/0021-9517(80)90072-X
J SEOANE, Ethylene oxidation to acetic acid with Pd-V2O5 type catalysts: I. Gas-solid reactions Journal of Catalysis. ,vol. 63, pp. 182- 190 ,(1980) , 10.1016/0021-9517(80)90071-8
Fernanda Gonçalves, Paulo RS Medeiros, Jean G Eon, Lucia G Appel, None, Active sites for ethanol oxidation over SnO2-supported molybdenum oxides Applied Catalysis A: General. ,vol. 193, pp. 195- 202 ,(2000) , 10.1016/S0926-860X(99)00430-5
Jon G. McCarty, Kinetics of PdO combustion catalysis Catalysis Today. ,vol. 26, pp. 283- 293 ,(1995) , 10.1016/0920-5861(95)00150-7
L. Tessier, E. Bordes, M. Gubelmann-Bonneau, Active specie on vanadium-containing catalysts for the selective oxidation of ethane to acetic acid Catalysis Today. ,vol. 24, pp. 335- 340 ,(1995) , 10.1016/0920-5861(95)00055-K
A EVNIN, Heterogeneously catalyzed vapor-phase oxidation of ethylene to acetaldehyde Journal of Catalysis. ,vol. 30, pp. 109- 117 ,(1973) , 10.1016/0021-9517(73)90057-2
E THORSTEINSON, The oxidative dehydrogenation of ethane over catalysts containing mixed oxides of molybdenum and vanadium Journal of Catalysis. ,vol. 52, pp. 116- 132 ,(1978) , 10.1016/0021-9517(78)90128-8