Hydrogen diffusion and effect of grain size on hydrogenation kinetics in magnesium hydrides

作者: X Yao , ZH Zhu , HM Cheng , GQ Lu , None

DOI: 10.1557/JMR.2008.0063

关键词: Chemical engineeringDehydrogenationDissociation (chemistry)Inorganic chemistryMagnesiumMaterials scienceHydrogen vehicleMetalActivation energyHydrogenGrain size

摘要: Hydrogenation and dehydrogenation of metal hydrides are great interest because their potential in on-board applications for hydrogen vehicles. This paper aims to study diffusion hydrides, which is generally considered be a controlling factor hydrogenation/dehydrogenation. The present work first calculated temperature-dependent coefficients by theoretical model incorporated with experimental data Mg-based system accordingly the activation energy. grain size effect on nanoscale was also investigated.

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