Investigation on preparation and mechanical properties of W–Cu–Zn alloy with low W–W contiguity and high ductility

作者: Lingling Zheng , Jinxu Liu , Shukui Li , Guohui Wang , Wenqi Guo

DOI: 10.1016/J.MATDES.2015.07.106

关键词: BrassPrecipitation hardeningTungstenAlloyDuctilitySpark plasma sinteringMaterials scienceMicrostructureMetallurgyRelative density

摘要: Abstract In order to improve the mechanical properties of W–Cu alloy, W–Cu–Zn alloys with low W–W contiguity were fabricated by three different preparation methods. For first method, mixed powder copper-coated tungsten and Zn was sintered SPS (Spark Plasma Sintering) process. second processed CIP (Cold Isostatic Pressing) before SPS. third a skeleton prepared CIP, then infiltrated H70 brass. The microstructure, failure mechanism investigated. results show that alloy method achieves high relative density 98.4% 10%. exhibits dynamic compressive strength 1000 MPa, critical strain 0.7. Cu-Zn matrix is composed α-phase Cu–Zn Cu3Zn particles. homogeneous distribution in manifests good solution strengthening effect uniformly distributed particles has strong precipitation effect, which are both responsible for evidently enhanced properties.

参考文章(19)
Jiudong Xu, Gang Yu, Bonian Hu, Jun Zhang, Qizhi Dong, XueYuan Zhang, Preparation of copper coated tungsten powders by intermittent electrodeposition Powder Technology. ,vol. 264, pp. 561- 569 ,(2014) , 10.1016/J.POWTEC.2014.06.005
Lianmeng Zhang, Wenshu Chen, Guoqiang Luo, Pingan Chen, Qiang Shen, Chuanbin Wang, Low-temperature densification and excellent thermal properties of W–Cu thermal-management composites prepared from copper-coated tungsten powders Journal of Alloys and Compounds. ,vol. 588, pp. 49- 52 ,(2014) , 10.1016/J.JALLCOM.2013.11.003
Pingan Chen, Qiang Shen, Guoqiang Luo, Meijuan Li, Lianmeng Zhang, The mechanical properties of W–Cu composite by activated sintering International Journal of Refractory Metals & Hard Materials. ,vol. 36, pp. 220- 224 ,(2013) , 10.1016/J.IJRMHM.2012.09.001
N.M Hwang, Y.J Park, D-Y Kim, D.Y Yoon, Activated sintering of nickel-doped tungsten: Approach by grain boundary structural transition Scripta Materialia. ,vol. 42, pp. 421- 425 ,(2000) , 10.1016/S1359-6462(99)00344-9
Wenshu Chen, Guoqiang Luo, Meijuan Li, Qiang Shen, Chuanbin Wang, Lianmeng Zhang, None, Effect of 2,2′-dipyridyl on the plating rate, microstructure and performance of copper-coated tungsten composite powders prepared using electroless plating Applied Surface Science. ,vol. 301, pp. 85- 90 ,(2014) , 10.1016/J.APSUSC.2014.01.107
Lai-Ma Luo, Ze-Long Lu, Xin-Min Huang, Xiao-Yue Tan, Guang-Nan Luo, Ji-Gui Cheng, Xiang Zan, Xiao-Yong Zhu, Yu-Cheng Wu, Fabrication of W–Cu/La2O3 composite powder with a novel pretreatment prepared by electroless plating and its sintering characterization International Journal of Refractory Metals & Hard Materials. ,vol. 48, pp. 1- 4 ,(2015) , 10.1016/J.IJRMHM.2014.07.020
M. Amirjan, K. Zangeneh-Madar, N. Parvin, Evaluation of microstructure and contiguity of W/Cu composites prepared by coated tungsten powders International Journal of Refractory Metals & Hard Materials. ,vol. 27, pp. 729- 733 ,(2009) , 10.1016/J.IJRMHM.2008.12.008
Pingan Chen, Guoqiang Luo, Meijuan Li, Qiang Shen, Lianmeng Zhang, Effects of Zn additions on the solid-state sintering of W–Cu composites Materials & Design. ,vol. 36, pp. 108- 112 ,(2012) , 10.1016/J.MATDES.2011.10.006
Zhang-Jian Zhou, Juan Du, Shu-Xiang Song, Zhi-Hong Zhong, Chang-Chun Ge, Microstructural characterization of W/Cu functionally graded materials produced by a one-step resistance sintering method Journal of Alloys and Compounds. ,vol. 428, pp. 146- 150 ,(2007) , 10.1016/J.JALLCOM.2006.03.073
Seong-Hyeon Hong, Byoung-Kee Kim, Zuhair A. Munir, Synthesis and consolidation of nanostructured W–10–40 wt.% Cu powders Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 405, pp. 325- 332 ,(2005) , 10.1016/J.MSEA.2005.06.015