Side Group Modified Polysiloxanes

作者: B. Boutevin , F. Guida-Pietrasanta , A. Ratsimihety

DOI: 10.1007/978-94-011-3939-7_3

关键词: SiloxaneFunctional groupCondensation polymerPolymerArylenePolymer chemistryAlkoxy groupMonomerPendant groupChemistry

摘要: The chemistry and technology of siloxane-based polymers, or silicones, is a very broad still growing research area owing to their many unique properties such as thermal oxidative stability, low surface tension, gas permeability, excellent dielectric properties, physiological inertness moisture resistance [1–3]. Because these silicones find tremendous number applications. Modifications polysiloxane side groups are extensively explored in order obtain polymers with special make them chemically active, thus giving access new industrial Polysiloxanes may be silicon-functional, i.e. the functional group, X, directly attached silicon atom (Si-X), organofunctional, group fixed via Si-C alkylene arylene (Si-R-X). most important include hydrogen, vinyl, chloro, hydroxy, mercapto, alkoxy, cyano, methacryloxy amino groups. There three general routes modified polysiloxanes: modification polysiloxanes, polycondensation bisilafunctional monomers ring-opening polymerisation cyclosiloxanes.

参考文章(144)
Julian Chojnowski, Krystyna Rózga, Synthesis of linear polysiloxanes with electron-donating organophosphorus pendant groups by kinetically controlled ring-opening polymerization Journal of Inorganic and Organometallic Polymers and Materials. ,vol. 2, pp. 297- 317 ,(1992) , 10.1007/BF00777248
Silicon in Polymer Synthesis Springer Berlin Heidelberg. ,(1996) , 10.1007/978-3-642-79175-8
John L. Speier, HOMOGENEOUS CATALYSIS OF HYDROSILATION BY TRANSITION METALS Advances in Organometallic Chemistry. ,vol. 17, pp. 407- 447 ,(1979) , 10.1016/S0065-3055(08)60328-7
Adel Hajaiej, Xavier Coqueret, Alain Lablache-Combier, Claude Loucheux, Functionalization of polysiloxanes by esterification of pendant epoxy groups: Cross‐linkable liquid polymers containing photo‐dimerizable ester units Macromolecular Chemistry and Physics. ,vol. 190, pp. 327- 340 ,(1989) , 10.1002/MACP.1989.021900211
Wojciech Duczmal, Włodzimierz Urbaniak, Bogdan Marciniec, Catalysis of hydrosilylation Journal of Organometallic Chemistry. ,vol. 317, pp. 85- 92 ,(1986) , 10.1016/S0022-328X(00)99347-1
Helmut Ringsdorf, Arnold Schneller, Liquid crystalline side chain polymers with low glass transition temperatures Die Makromolekulare Chemie, Rapid Communications. ,vol. 3, pp. 557- 562 ,(1982) , 10.1002/MARC.1982.030030806
Martin Lux, Peter Strohriegl, Hartwig Höcker, Polymers with pendant carbazolyl groups, 2. Synthesis and characterization of some novel liquid crystalline polysiloxanes Macromolecular Chemistry and Physics. ,vol. 188, pp. 811- 820 ,(1987) , 10.1002/MACP.1987.021880415