Imaging phonon excitation with atomic resolution.

作者: H. Gawronski , M. Mehlhorn , K. Morgenstern

DOI: 10.1126/SCIENCE.1152473

关键词: ExcitationPhononElectron scatteringQuantum tunnellingSurface layerAtomic physicsInelastic electron tunneling spectroscopyInelastic scatteringScanning tunneling microscopeChemistry

摘要: Inelastic electron tunneling spectroscopy at low temperatures was used to investigate vibrations of Au(111) and Cu(111). The low-energy peaks 9 millielectron volts (meV) on 21 meV Cu(111) are attributed phonons surfaces. On Au(111), the phonon energy is not influenced by different stacking surface atoms, but it considerably atomic distances within layer. spatial variation excitation measured in inelastic maps which display resolution. This resolution explained terms site-specific probabilities.

参考文章(28)
H. Gawronski, K. Morgenstern, K.-H. Rieder, Electronic excitation of ice monomers on Au(111) by scanning tunneling microscopy. Vibrational spectra and induced processes European Physical Journal D. ,vol. 35, pp. 349- 353 ,(2005) , 10.1140/EPJD/E2005-00224-4
C. Untiedt, G. Rubio Bollinger, S. Vieira, N. Agraït, Quantum interference in atomic-sized point contacts Physical Review B. ,vol. 62, pp. 9962- 9965 ,(2000) , 10.1103/PHYSREVB.62.9962
M. F. Crommie, C. P. Lutz, D. M. Eigler, Imaging standing waves in a two-dimensional electron gas Nature. ,vol. 363, pp. 524- 527 ,(1993) , 10.1038/363524A0
L. Vitali, M. A. Schneider, K. Kern, L. Wirtz, A. Rubio, Phonon and plasmon excitation in inelastic electron tunneling spectroscopy of graphite Physical Review B. ,vol. 69, pp. 121414- ,(2004) , 10.1103/PHYSREVB.69.121414
B. C. Stipe, M. A. Rezaei, W. Ho, Localization of Inelastic Tunneling and the Determination of Atomic-Scale Structure with Chemical Specificity Physical Review Letters. ,vol. 82, pp. 1724- 1727 ,(1999) , 10.1103/PHYSREVLETT.82.1724
X. H. Qiu, G. V. Nazin, W. Ho, Vibronic States in Single Molecule Electron Transport Physical Review Letters. ,vol. 92, pp. 206102- ,(2004) , 10.1103/PHYSREVLETT.92.206102
Michael Mehlhorn, Heiko Gawronski, Lorenz Nedelmann, Alexander Grujic, Karina Morgenstern, An instrument to investigate femtochemistry on metal surfaces in real space. Review of Scientific Instruments. ,vol. 78, pp. 033905- ,(2007) , 10.1063/1.2432244
Nicolás Agraït, Carlos Untiedt, Gabino Rubio-Bollinger, Sebastián Vieira, Onset of energy dissipation in ballistic atomic wires. Physical Review Letters. ,vol. 88, pp. 216803- ,(2002) , 10.1103/PHYSREVLETT.88.216803
N. Lorente, M. Persson, Theory of single molecule vibrational spectroscopy and microscopy. Physical Review Letters. ,vol. 85, pp. 2997- 3000 ,(2000) , 10.1103/PHYSREVLETT.85.2997
Karina Morgenstern, Karl-Heinz Rieder, Formation of the cyclic ice hexamer via excitation of vibrational molecular modes by the scanning tunneling microscope Journal of Chemical Physics. ,vol. 116, pp. 5746- 5752 ,(2002) , 10.1063/1.1453965