Formation of the cyclic ice hexamer via excitation of vibrational molecular modes by the scanning tunneling microscope
作者： Karina Morgenstern , Karl-Heinz Rieder
DOI: 10.1063/1.1453965
关键词:
摘要: Starting from water monomers adsorbed on Cu(111), we have induced the formation of small ice clusters via tip a low temperature scanning tunnelling microscope. We show that diffusion, formation, and structural changes are by electrons coupling to vibrational modes molecule. The manipulation transfers enough energy into system induce stable both two-dimensional three-dimensional ones, including important cyclic hexamer. Only develop localized gap around Fermi ≈76 meV, which varies for different positions cluster.
scitation.org
harvard.edu
core.ac.uk
aip.org
sci-hub.se 参考文章(35)
Mark R. Viant, Mac G. Brown, Jeff D. Cruzan, Richard J. Saykally, Michel Geleijns, Ad van der Avoird, Quantitative characterization of the (D2O)(3) torsional manifold by terahertz laser spectroscopy and theoretical analysis Journal of Chemical Physics. ,vol. 110, pp. 4369- 4381 ,(1999) , 10.1063/1.478319
George A. Jeffrey, Wolfram Saenger, Hydrogen Bonding in Biological Structures ,(1991)
J. A. STROSCIO, D. M. EIGLER, Atomic and molecular manipulation with the scanning tunneling microscope. Science. ,vol. 254, pp. 1319- 1326 ,(1991) , 10.1126/SCIENCE.254.5036.1319
Robin J. Speedy, Jeffry D. Madura, William L. Jorgensen, Network topology in simulated water The Journal of Physical Chemistry. ,vol. 91, pp. 909- 913 ,(1987) , 10.1021/J100288A029
B. J. Hinch, L. H. Dubois, Stable and metastable phases of water adsorbed on Cu(111) Journal of Chemical Physics. ,vol. 96, pp. 3262- 3268 ,(1992) , 10.1063/1.461971
K. Liu, M. G. Brown, C. Carter, R. J. Saykally, J. K. Gregory, D. C. Clary, Characterization of a cage form of the water hexamer Nature. ,vol. 381, pp. 501- 503 ,(1996) , 10.1038/381501A0
Patricia A. Thiel, Theodore E. Madey, The interaction of water with solid surfaces: Fundamental aspects Surface Science Reports. ,vol. 7, pp. 211- 385 ,(1987) , 10.1016/0167-5729(87)90001-X
K. Nauta, Formation of cyclic water hexamer in liquid helium: the smallest piece of Ice Science. ,vol. 287, pp. 293- 295 ,(2000) , 10.1126/SCIENCE.287.5451.293
Chak-tong Au, Juraj Breza, M.Wyn Roberts, Hydroxylation and dehydroxylation at Cu(III) surfaces Chemical Physics Letters. ,vol. 66, pp. 340- 343 ,(1979) , 10.1016/0009-2614(79)85030-7
Sotiris S. Xantheas, Thom H. Dunning, Ab initio studies of cyclic water clusters (H2O)n, n=1–6. I. Optimal structures and vibrational spectra Journal of Chemical Physics. ,vol. 99, pp. 8774- 8792 ,(1993) , 10.1063/1.465599