作者: H. Taube
DOI: 10.1016/S0065-2792(08)60251-4
关键词: Computational chemistry 、 Redox 、 Mechanism (philosophy) 、 Chemistry (relationship) 、 Oxidation state 、 Molecule 、 Gas phase 、 Metal ions in aqueous solution 、 Physical chemistry 、 Chemistry 、 Simple (philosophy)
摘要: Publisher Summary The principal concern in this chapter is the mechanism of reaction metal ions, which a change oxidation state takes place on reaction. Nevertheless, fundamental questions as to means by were until recently not formulated, let alone answered. general subject includes proper part problems specific chemistry, such are encounted reaction, for example, Fe++ with Mn04-: What steps system proceeds final products, and what properties intermediate states Mn (or Fe), must be involved complex over-all reaction? Important inorganic are, most they have been set aside attention directed rather description individual steps. It instructive consider some features data charge-transfer processes gas phase between simple molecules before considering systems complicated interactions central atoms solvent or other groups.