Mechanisms of Redox Reactions of Simple Chemistry

作者: H. Taube

DOI: 10.1016/S0065-2792(08)60251-4

关键词: Computational chemistryRedoxMechanism (philosophy)Chemistry (relationship)Oxidation stateMoleculeGas phaseMetal ions in aqueous solutionPhysical chemistryChemistrySimple (philosophy)

摘要: Publisher Summary The principal concern in this chapter is the mechanism of reaction metal ions, which a change oxidation state takes place on reaction. Nevertheless, fundamental questions as to means by were until recently not formulated, let alone answered. general subject includes proper part problems specific chemistry, such are encounted reaction, for example, Fe++ with Mn04-: What steps system proceeds final products, and what properties intermediate states Mn (or Fe), must be involved complex over-all reaction? Important inorganic are, most they have been set aside attention directed rather description individual steps. It instructive consider some features data charge-transfer processes gas phase between simple molecules before considering systems complicated interactions central atoms solvent or other groups.

参考文章(124)
Philip George, D. H. Irvine, Electron-transfer reactions between metallic ions, co-ordination complexes, and hœmoglobin J. Chem. Soc.. ,vol. 0, pp. 587- 593 ,(1954) , 10.1039/JR9540000587
Frederick R. Duke, Reactions involving like-charged ions; a neutral intermediate in alkaline permanganate oxidations. Journal of the American Chemical Society. ,vol. 70, pp. 3975- 3978 ,(1948) , 10.1021/JA01192A002
Henry. Taube, Harold. Dodgen, Applications of Radioactive Chlorine to the Study of the Mechanisms of Reactions Involving Changes in the Oxidation State of Chlorine Journal of the American Chemical Society. ,vol. 71, pp. 3330- 3336 ,(1949) , 10.1021/JA01178A016
J. C. Sullivan, Donald Cohen, J. C. Hindman, ISOTOPIC EXCHANGE REACTIONS OF NEPTUNIUM IONS IN SOLUTION. II. THE Np(IV)- Np(V) EXCHANGE Journal of the American Chemical Society. ,vol. 76, pp. 3672- 3674 ,(1954) , 10.1021/JA01646A006
W. L. Reynolds, R. W. Lumry, Role of Water in Oxidation‐Reduction Reactions Journal of Chemical Physics. ,vol. 23, pp. 2460- 2461 ,(1955) , 10.1063/1.1741928
Arthur C. Wahl, Charles F. Deck, RATE OF THE FERROCYANIDE-FERRICYANIDE EXCHANGE REACTION1 Journal of the American Chemical Society. ,vol. 76, pp. 4054- 4055 ,(1954) , 10.1021/JA01644A078
Jack J. Grossman, Clifford S. Garner, Exchange of Radiocobalt between the Hexammines of Cobalt(II) and Cobalt(III) in Liquid Ammonia Journal of Chemical Physics. ,vol. 28, pp. 268- 270 ,(1958) , 10.1063/1.1744103
Wendell M. Latimer, Kenneth S. Pitzer, Cyril M. Slansky, The Free Energy of Hydration of Gaseous Ions, and the Absolute Potential of the Normal Calomel Electrode Journal of Chemical Physics. ,vol. 7, pp. 108- 111 ,(1939) , 10.1063/1.1750387
C. B. Amphlett, Isotopic exchange between different oxidation states in aqueous solution Quarterly Reviews, Chemical Society. ,vol. 8, pp. 219- 249 ,(1954) , 10.1039/QR9540800219
Donald Cohen, J. C. Sullivan, E. S. Amis, J. C. Hindman, Isotopic Exchange Reactions of Neptunium Ions in Solution. IV. The Effect of Variation of Dielectric Constant on the Rate of the Np(V)-Np(VI) Exchange1 Journal of the American Chemical Society. ,vol. 78, pp. 1543- 1545 ,(1956) , 10.1021/JA01589A009