Ketone-directed peracid epoxidation of cyclic alkenes
作者： Alan Armstrong , Paul A. Barsanti , Paul A. Clarke , Anthony Wood
DOI: 10.1039/P19960001373
关键词: Dioxirane 、 Ketone 、 Selectivity 、 Chemistry 、 Cyclic Alkenes 、 Labelling 、 Organic chemistry
摘要: Ketone carbonyl groups are shown to direct the peracid epoxidation of cyclic alkenes with greater selectivity than that displayed by esters. An 18O labelling study is used show a dioxirane intermediate not involved in these reactions.
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