Virial expansion and an improved equation of state for the hard convex molecule system
作者： I. Nezbeda
DOI: 10.1016/0009-2614(76)85246-3
关键词: Boyle temperature 、 Radial distribution function 、 Regular polygon 、 Thermodynamics 、 Chemistry 、 Virial coefficient 、 Virial expansion 、 Equation of state 、 Virial theorem 、 Mathematical analysis 、 Series (mathematics)
摘要: Abstract The fourth virial coefficient of hard spherocylinders is calculated using the Monte-Carlo technique and fifth one by means a recurrence formula. From an analysis reduced series new equation state then developed which provides excellent agreement with pseudoexperimental data.
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