Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols
作者： Rongguo Ren , Zhen Wu , Chen Zhu
DOI: 10.1039/C6CC01843B
关键词: Reaction conditions 、 Alpha cleavage 、 Bond formation 、 Bond cleavage 、 Alkyl 、 Photochemistry 、 Medicinal chemistry 、 Manganese 、 Catalysis 、 Chemistry 、 Regioselectivity
摘要: A manganese-catalyzed regioselective sp3 C–S bond formation through C–C cleavage of cyclobutanols is described. variety primary and secondary alkyl thioethers are efficiently prepared under mild reaction conditions. The mechanistic pathways involving radical-mediated tandem proposed.
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