Cluster chemistry: XXXVI. Hydrogenation of an open Ru5 cluster: Excission of a ruthenium carbonyl fragment. X-ray structure of Ru4(μ-H)3(μ4-η2, P-HC2PPh2)(μ-PPh2)(CO)10☆
作者： Michael I. Bruce , Michael L. Williams , Brian W. Skelton , Allan H. White
DOI: 10.1016/0022-328X(85)87203-X
关键词: Inorganic compound 、 Crystal structure 、 Chemistry 、 Cluster chemistry 、 Ligand 、 X-ray crystallography 、 Ruthenium 、 Cluster (physics) 、 Crystallography 、 Stereochemistry 、 Molecule
摘要: Abstract Hydrogenation (25° C, 10 atm) of Ru 5 (μ -η 2 , P -C PPh )(μ-PPh )(CO) 13 gave 4 (μ-H) (CO) 12 and the tetranuclear 3 -HC ; an X-ray structure shows presence a HCCPPh ligand bonded to all four atoms metallo-ligated triangular cluster.
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sci-hub.se 参考文章(6)
John R. Shapley, Joon Taik Park, Melvyn Rowen Churchill, Clifford Bueno, Harvey J. Wasserman, Remarkably facile osmium-osmium bond cleavage in the reaction of H2Os3(CO)10 with a tungsten carbyne. Crystal structures of CpWOs3(CO)11[C(O)CH2C6H4Me] and Cp2W2Os(CO)7[C2(C6H4Me)2] Journal of the American Chemical Society. ,vol. 103, pp. 7385- 7387 ,(1981) , 10.1021/JA00414A081
Melvyn Rowen. Churchill, Clifford. Bueno, Harvey J. Wasserman, X-ray structural study of (.eta.5-C5H5)2W2Os(CO)7[.mu.3-MeC6H4C.tplbond.CC6H4Me]. An unusual example of two isomers of a complex in an ordered single crystal Inorganic Chemistry. ,vol. 21, pp. 640- 644 ,(1982) , 10.1021/IC00132A035
Michael I. Bruce, Brian K. Nicholson, Michael L. Williams, XV. Formation of an η2-olefin derivative of Ru3(CO)12, and its conversion to an η2-Alkyne-hydrido complex: Crystal and molecular structures of Ru3(μ-P-η2-CH2CHC6H4PPh2)(CO)10 and H2Ru3(μ3-P,η2-HCCC6H4PPh2)(CO)8 Journal of Organometallic Chemistry. ,vol. 243, pp. 69- 78 ,(1983) , 10.1016/0022-328X(83)80222-8
Richard D. Adams, Li Wu Yang, Weak metal-metal bonds in an "electron-rich" cluster. The synthesis and x-ray crystallographic characterization of Os4(CO)12(.mu.3-S)2 and Os6(CO)16(.mu.4-S)(.mu.3-S) Journal of the American Chemical Society. ,vol. 104, pp. 4115- 4117 ,(1982) , 10.1021/JA00379A012
Shane A. MacLaughlin, Nicholas J. Taylor, Arthur J. Carty, Acetylene additions to saturated and unsaturated clusters: four-electron addition with and without carbon monoxide loss Organometallics. ,vol. 3, pp. 392- 399 ,(1984) , 10.1021/OM00081A012
Arthur J. Carty, Shane A. MacLaughlin, Jodi Van Wagner, Nicholas J. Taylor, Structural versatility of Ru4 butterflies. The molecular structures of Ru4(CO)13(.mu.-PPh2)(.mu.-.eta.2-C.tplbond.C-t-Bu) and Ru4(CO)8(.mu.-PPh2)2(.mu.-.eta.2-C.tplbond.C-t-Bu)(.mu.3-.eta.2-C.tplbond.C-t-Bu)(Ph2PC.tplbond.C-t-Bu).1/2C6H14: clusters with almost planar metal frameworks Organometallics. ,vol. 1, pp. 1013- 1015 ,(1982) , 10.1021/OM00067A024