Electron Transfer-Catalysed Substitution Reactions of Metal Cluster Carbonyls
作者： Michael I. Bruce
DOI: 10.1007/978-94-009-0877-2_28
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摘要: This article summarises the scope of radical anion (alkali metal diphenylketyl) initiated substitution reactions cluster carbonyls. The method has been applied mainly to Ru3(CO)12 but several other homo- and hetero-metallic clusters containing Fe, Ru, Os, Co, Rh, or Ir reported. Some suggestions are made concerning mechanism these reactions, which probably proceed by a chain process, it is clear that present information does not provide an unequivocal answer this problem.
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