Thermal cycle stability of a novel glass-mica composite seal for solid oxide fuel cells : Effect of glass volume fraction and stresses

作者: Yeong-Shyung Chou , Jeffry W. Stevenson , Prabhakar Singh

DOI: 10.1016/J.JPOWSOUR.2005.03.213

关键词: OxideMicaForensic engineeringVolume (thermodynamics)MicrostructureVolume fractionComposite materialMaterials scienceSeal (mechanical)Composite numberSolid oxide fuel cell

摘要: Abstract A novel glass–mica composite seal was developed based on a previously reported concept of “infiltrated” mica seals for solid oxide fuel cells. Ba–Al–Ca silicate sealing glass powder and Phlogopite flakes were mixed at volume fractions 10–50 vol.% to make the seals. The leak tested short-term thermal cycle stability as function fraction. Composite with 10 20 vol.% also under compressive stresses from 3 100 psi helium pressures 0.2 or 2 psi. Post-mortem microstructure analyses used characterize fracture (leak path) related high temperature leakages. Open circuit voltage tests dense 8YSZ electrolyte showed very good over 250 cycles minute (

参考文章(17)
K. Scott Weil, Jin Yong Y. Kim, John S. Hardy, Use of Novel Ceramic-Metal Braze for Joining in High Temperature Electrochemical Devices Indacochea, J. E.; ASM International , Materials Park, OH, United States(US).. ,(2003)
R Zheng, S.R Wang, H.W Nie, T.-L Wen, SiO2–CaO–B2O3–Al2O3 ceramic glaze as sealant for planar ITSOFC Journal of Power Sources. ,vol. 128, pp. 165- 172 ,(2004) , 10.1016/J.JPOWSOUR.2003.10.005
Hans Peter Buchkremer, Detlev Stöver, Martin Bram, Stephan Reckers, Pere Drinovac, Josef Mönch, Rolf W. Steinbrech, Deformation behavior and leakage tests of alternate sealing materials for SOFC stacks Journal of Power Sources. ,vol. 138, pp. 111- 119 ,(2004) , 10.1016/J.JPOWSOUR.2004.06.041
Yeong-shyung Chou, Jeffry W. Stevenson, Lawrence A. Chick, Novel Compressive Mica Seals with Metallic Interlayers for Solid Oxide Fuel Cell Applications Journal of the American Ceramic Society. ,vol. 86, pp. 1003- 1007 ,(2003) , 10.1111/J.1151-2916.2003.TB03408.X
Yeong-Shyung Chou, Jeffry W. Stevenson, Novel infiltrated Phlogopite mica compressive seals for solid oxide fuel cells Journal of Power Sources. ,vol. 135, pp. 72- 78 ,(2004) , 10.1016/J.JPOWSOUR.2004.02.037
Wenxia Li, Kathy Hasinska, Matt Seabaugh, Scott Swartz, John Lannutti, Curvature in solid oxide fuel cells Journal of Power Sources. ,vol. 138, pp. 145- 155 ,(2004) , 10.1016/J.JPOWSOUR.2004.06.034
S Taniguchi, M Kadowaki, T Yasuo, Y Akiyama, Y Miyake, K Nishio, Improvement of thermal cycle characteristics of a planar-type solid oxide fuel cell by using ceramic fiber as sealing material Journal of Power Sources. ,vol. 90, pp. 163- 169 ,(2000) , 10.1016/S0378-7753(00)00405-5
Jean Duquette, Anthony Petric, Silver wire seal design for planar solid oxide fuel cell stack Journal of Power Sources. ,vol. 137, pp. 71- 75 ,(2004) , 10.1016/J.JPOWSOUR.2004.05.038
W.B Hanson, K.I Ironside, J.A Fernie, Active metal brazing of zirconia Acta Materialia. ,vol. 48, pp. 4673- 4676 ,(2000) , 10.1016/S1359-6454(00)00256-1