Volatile Lactones — (5S,S)‐5‐Methyl‐3‐(methylalkyl)furan‐2(5H)‐ones — Identified in the Submerged Cultivation of Streptomyces Avermitilis
作者： Tomáš Řezanka , Karel Sigler
关键词: Stereochemistry 、 Streptomyces avermitilis 、 Chemical decomposition 、 Furan 、 Chemistry 、 Carbon-13 NMR
摘要: Six new compounds have been identified in the volatile fractions produced during submerged cultivation of Streptomyces avermitilis. By recording GC/MS, GC/FTIR, CD, 1H and 13C NMR data by performing chemical degradation experiments, these were determined to be (5S,S)-5-methyl-3-(methylalkyl)furan-2(5H)-ones. Herein, existence lactones with an anteiso structure side-chain is thus documented for first time. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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