Resonant electron scattering from benzene chemisorbed on Pt(111)
作者： Franz Cemic , Olaf Dippel , Eckart Hasselbrink
DOI: 10.1016/0039-6028(95)00781-4
关键词: Molecular vibration 、 High resolution electron energy loss spectroscopy 、 Vibronic coupling 、 Electron scattering 、 Ion 、 Atomic physics 、 Excited state 、 Chemistry 、 Chemisorption 、 Resonance
摘要: Abstract High resolution electron energy loss spectroscopy (HREELS) has been used to locate a negative ion resonance at about 2.1 eV beam in benzene chemisorbed on Pt(111). We determine the predominant excitation mechanisms for several vibrational modes of adsorbate. A group theoretical analysis resonantly excited is deduce symmetry adsorbate complex. Emphasis laid influence vibronic coupling neighbouring resonances. come conclusion that complex should be either C3v(σv) or Cs(σv).
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