Platinum source compositions for chemical vapor deposition of platinum

作者: Thomas H. Baum , Sofia Pombrik , Peter S. Kirlin

DOI:

关键词: Deposition (phase transition)SolventSubstrate (chemistry)TrimethylsilylPlatinumChemistryReagentChemical vapor depositionInorganic chemistryTrifluoromethyl

摘要: A platinum source reagent liquid solution, comprising: (i) at least one compound selected from the group consisting of compunds formulae: (A) RCpPt(IV)R'3 compounds, formula (I), wherein R is hydrogen, methyl, ethyl, i-propyl, n-propyl, n-butyl, i-butyl, t-butyl, trimethylsilyl and methyl; each R' idependently (B) Pt(β-diketonates)2 (II), independently trifluoromethyl, perfluoroethyl, perfluoro-n-propyl, (ii) a solvent medium therefor. The solutions invention are readily employed in chemical vapor deposition process system including delivery apparatus for volatilizing solution transporting resulting to reactor on substrate mounted CVD reactor.

参考文章(15)
John Melngailis, Tao Tao, Ion beam induced deposition of metals ,(1990)
Alfred A. Zinn, Lutz Brandt, Herbert D. Kaesz, Robert F. Hicks, Chemical Vapor Deposition of Platinum, Palladium and Nickel The Chemistry of Metal CVD. pp. 329- 355 ,(2007) , 10.1002/9783527615858.CH7
Ravindra K. Kanjolia, Benjamin C. Hui, Liquid indium source ,(1994)
Robert F. Hicks, Herbert D. Kaesz, Catalysis in organometallic CVD of thin metal films ,(1992)
Robin A. Gardiner, Peter S. Kirlin, Duncan W. Brown, Method of forming a superconducting oxide layer by MOCVD ,(1992)
Robert F. Hicks, Dagiang Xu, Herbert D. Kaesz, Low temperature organometallic deposition of metals ,(1989)
Ziling Xue, M. Jane Strouse, David K. Shuh, Carolyn B. Knobler, Herbert D. Kaesz, Robert F. Hicks, R. Stanley Williams, Characterization of (methylcyclopentadienyl)trimethylplatinum and low-temperature organometallic chemical vapor deposition of platinum metal Journal of the American Chemical Society. ,vol. 111, pp. 8779- 8784 ,(1989) , 10.1021/JA00206A002
Frederick D. Lewis, Gwen D. Salvi, Platinum(II) bis({beta}-diketonates) as photoactivated hydrosilation catalysts Inorganic Chemistry. ,vol. 34, pp. 3182- 3189 ,(1995) , 10.1021/IC00116A008
Ziling Xue, Hareesh Thridandam, Herbert D. Kaesz, Robert F. Hicks, Organometallic chemical vapor deposition of platinum. Reaction kinetics and vapor pressures of precursors Chemistry of Materials. ,vol. 4, pp. 162- 166 ,(1992) , 10.1021/CM00019A032
B. S. Kwak, P. N. First, A. Erbil, B. J. Wilkens, J. D. Budai, M. F. Chisholm, L. A. Boatner, Study of epitaxial platinum thin films grown by metalorganic chemical vapor deposition Journal of Applied Physics. ,vol. 72, pp. 3735- 3740 ,(1992) , 10.1063/1.352293