Structural diversity through ligand flexibility: two novel metal-organic nets via ligand-to-ligand cross-linking of "paddlewheels".
作者： Wenge Qiu , Jason A. Perman , Łukasz Wojtas , Mohamed Eddaoudi , Michael J. Zaworotko
DOI: 10.1039/C0CC03270K
关键词: Trigonal prismatic molecular geometry 、 Flexibility (anatomy) 、 Metal 、 Ligand 、 Net (polyhedron) 、 Crystallography 、 Solvothermal reaction 、 Structural diversity 、 Materials science
摘要: Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagome lattices formula [Cu2(L)]n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) the first example pillared net.
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