ELECTROLYTE-INDUCED SPIN-STATE TRANSITION OF IRON IN IRON(III) PHTHALOCYANINE
作者： Nagao Kobayashi , Masami Koshiyama , Yoko Ishikawa , Tetsuo Osa , Hirofusa Shirai
DOI: 10.1246/CL.1984.1633
关键词: Spin states 、 Magnetic susceptibility 、 Spectroscopy 、 Chemistry 、 Absorption (chemistry) 、 Phthalocyanine 、 Bromide 、 Electrolyte 、 Magnetic circular dichroism 、 Inorganic chemistry 、 General chemistry
摘要: Magnetic susceptibility, magnetic circular dichroism(MCD), UV-visible absorption, and ESR spectroscopy have revealed that spin state of iron in 1,2,8,9,15,16,22,23-octadecyloxycarbonylphthalocyaninatoiron(III) dissolved CH2Cl2 or CHCl3 changes from high-spin to low-spin by the addition ca. 10 equiv. tetrabutylammoniumchloride (Bu4NCl) and/or -bromide(Bu4NBr), (electrolytes).
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