Mechanism of uranium(IV) extraction with CYANEX 302 in kerosene from nitrate medium
作者： N. Abdel Rahman , J. A. Daoud , H. F. Aly
DOI: 10.1023/B:JRNC.0000011756.77475.17
关键词: Uranium 、 Inorganic chemistry 、 Nitric acid 、 Chemical reaction 、 Kerosene 、 Extraction (chemistry) 、 Chemistry 、 Kinetics 、 Reaction mechanism 、 Stoichiometry 、 Analytical chemistry 、 Spectroscopy 、 Public Health, Environmental and Occupational Health 、 Nuclear Energy and Engineering 、 Pollution 、 Health, Toxicology and Mutagenesis 、 Radiology Nuclear Medicine and imaging
摘要: The extraction of U(IV) by bis(2,4,4-trimethylpentyl) monothiophosphinic acid (CYANEX 302) in kerosene from nitric solution has been investigated under equilibrium conditions. effects the different parameters affecting process were studied and stoichiometry extracted species was elucidated. kinetics this also using a stirred Lewis cell. rate as well temperature separately investigated. results are interpreted reaction mechanism where is controlled chemical at interface rather than bulk phase.
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akademiai.com参考文章(7)
F. Fairbrother, A text-book of quantitative inorganic analysis Journal of Inorganic and Nuclear Chemistry. ,vol. 25, pp. 745- ,(1963) , 10.1016/0022-1902(63)80176-1
Jan Rydberg, Claude Musikas, Gregory R. Choppin, Principles and practices of solvent extraction M. Dekker. ,(1992)
James H. Espenson, Chemical kinetics and reaction mechanisms ,(1981)
Pier Roberto Danesi, Renato Chiarizia, Charles F. Coleman, The Kinetics of Metal Solvent Extraction Critical Reviews in Analytical Chemistry. ,vol. 10, pp. 1- 126 ,(1980) , 10.1080/10408348008542724
G. Ionova, S. Ionov, C. Rabbe, C. Hill, C. Madic, R. Guillaumont, J. C. Krupa, MECHANISM OF TRIVALENT ACTINIDE/LANTHANIDE SEPARATION USING BIS(2,4,4-TRIMETHYLPENTYL) DITHIOPHOSPHINIC ACID (CYANEX 301) AND NEUTRAL O-BEARING CO-EXTRACTANT SYNERGISTIC MIXTURES Solvent Extraction and Ion Exchange. ,vol. 19, pp. 391- 414 ,(2001) , 10.1081/SEI-100103277
Yongjun Zhu, Jing Chen, Rongzhou Jiao, Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301 Solvent Extraction and Ion Exchange. ,vol. 14, pp. 61- 68 ,(1996) , 10.1080/07366299608918326
J. A. Daoud, N. Abdel Rahman, H. F. Aly, Kinetic studies on the extraction of U(IV) by TBP in kerosene from nitrate medium Journal of Radioanalytical and Nuclear Chemistry. ,vol. 221, pp. 41- 44 ,(1997) , 10.1007/BF02035240