Liquid–liquid extraction of uranium(VI) using cyanex 272 in toluene from sodium salicylate medium

作者: N Madane , G Nikam , K Mahanwar , B Mohite , None

DOI: 10.1007/S10967-010-0913-X

关键词:

摘要: Liquid–liquid extraction and separation studies of uranium have been carried out from sodium salicylate media using cyanex 272 in toluene. Uranium was quantitatively extracted by 1 × 10−3 M with 5 10−4 The uranium(VI) stripped the organic phase 1.0 hydrochloric acid determined spectrophotometrically arsenazo(III) at 660 nm. effect concentration salicylate, extractant, diluents, metal ion strippants has studied. Separation other elements achieved binary as well multicomponent mixtures. method extended for determination geological samples. is simple, rapid selective good reproducibility (approximately ± 2%).

参考文章(20)
F. Fairbrother, A text-book of quantitative inorganic analysis Journal of Inorganic and Nuclear Chemistry. ,vol. 25, pp. 745- ,(1963) , 10.1016/0022-1902(63)80176-1
B. Gupta, P. Malik, A. Deep, Extraction of uranium, thorium and lanthanides using Cyanex-923: Their separations and recovery from monazite Journal of Radioanalytical and Nuclear Chemistry. ,vol. 251, pp. 451- 456 ,(2004) , 10.1023/A:1014890427073
S. M. Sawant, Solvent extraction of uranium(VI) using dibenzo-18-crown-6 in nitrobenzene from ammonium thiocyanate medium Journal of Radioanalytical and Nuclear Chemistry. ,vol. 249, pp. 613- 616 ,(2001) , 10.1023/A:1013206517457
B. Rajeswari, B. A. Dhawale, T. R. Bangia, J. N. Mathur, A. G. Page, Role of Cyanex-272 as an extractant for uranium in the determination of rare earths by ICP-AES Journal of Radioanalytical and Nuclear Chemistry. ,vol. 254, pp. 479- 483 ,(2002) , 10.1023/A:1021633920249
S. D. Dogmane, R. K. Singh, D. D. Bajpai, J. N. Mathur, Extraction of U(VI) by cyanex-272 Journal of Radioanalytical and Nuclear Chemistry. ,vol. 253, pp. 477- 482 ,(2002) , 10.1023/A:1020485923401
A. Senol, Liquid-liquid extraction of uranium(VI) from aqueous acidic solutions using Alamine, TBP and CYANEX systems Journal of Radioanalytical and Nuclear Chemistry. ,vol. 258, pp. 361- 372 ,(2003) , 10.1023/A:1026298023791
R. K. Singh, P. M. Dhadke, Extraction of U(VI), Zr(IV) and Th(IV) from perchlorate media, by PC-88A Journal of Radioanalytical and Nuclear Chemistry. ,vol. 254, pp. 607- 612 ,(2002) , 10.1023/A:1021666827517
Sun Guoxin, Cui Yu, Li Yexin, Zhang Zhenwei, Sun Sixiu, Extraction of U(VI) with unsymmetrical N-methyl-N-octyl alkylamides in toluene Journal of Radioanalytical and Nuclear Chemistry. ,vol. 264, pp. 711- 713 ,(2005) , 10.1007/S10967-005-0776-8
N. Abdel Rahman, J. A. Daoud, H. F. Aly, Mechanism of uranium(IV) extraction with CYANEX 302 in kerosene from nitrate medium Journal of Radioanalytical and Nuclear Chemistry. ,vol. 258, pp. 597- 603 ,(2003) , 10.1023/B:JRNC.0000011756.77475.17