Transamidation of Primary Amides with Amines Using Hydroxylamine Hydrochloride as an Inorganic Catalyst
作者： C. Liana Allen , Benjamin N. Atkinson , Jonathan M. J. Williams
关键词: Primary (chemistry) 、 Hydroxylamine Hydrochloride 、 Organic chemistry 、 Amine gas treating 、 Amide 、 Catalysis 、 Chemistry
摘要: Metal-free catalysis: A method for the transamidation of primary amides with or secondary amines provides access to and tertiary amides, by utilizing catalytic quantities hydroxylamine hydrochloride activate chemically robust amide group (see scheme). mechanism activation through a hydrogen-bonding complex is proposed.
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