Ordered and twinned structure in hexagonal-based potassium tungsten bronze nanosheets
作者： Shuangfeng Jia , Hongqian Sang , Wenjing Zhang , Han Zhang , He Zheng
DOI: 10.1107/S0021889813026216
关键词: Metallurgy 、 Crystal growth 、 Bronze 、 Superstructure (condensed matter) 、 Crystal twinning 、 Potassium hydroxide 、 Crystallography 、 Materials science 、 Monoclinic crystal system 、 Potassium 、 Tungsten
摘要: Non-stoichiometric hexagonal-based potassium tungsten bronze (KxWO3) nanosheets were synthesized by oxidizing foil in hydroxide. The exhibited an ordered monoclinic superstructure as revealed X-ray diffraction patterns. Further detailed structural investigation employing electron microscopy techniques showed the coexistence of 120° rotation twinning variants phase, which may result from symmetry reduction induced arrangements K vacancies during crystal growth.
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