Impact of the adsorbate compressibility on the calculation of the micropore volume

摘要: Abstract The theory of micropore volume filling has been modified in taking into account the adsorbate compressibility. A new equation obtained for calculating from experimental value limit adsorption. estimations, with example benzene adsorption on activated carbons, show that because compressibility, real can exceed values calculated conventional Dubinin-Radushkevich by about 10% at room temperature, and this difference increases an increase temperature.