Solvent resistance and mechanical properties in thermoplastic elastomer blends prepared by dynamic vulcanization
作者： J. D. (Jack) Van Dyke , Marek Gnatowski , Andrew Burczyk
DOI: 10.1002/APP.28149
关键词: Materials science 、 Thermoplastic elastomer 、 Polymer blend 、 Nitrile rubber 、 Composite material 、 Butyl rubber 、 Polybutylene terephthalate 、 Thermoplastic 、 Natural rubber 、 Vulcanization
摘要: Dynamic vulcanization was used to prepare thermoplastic elastomer blends of nylon (polyamide), polypropylene (PP) and polybutylene terephthalate thermoplastics with chlorobutyl (CIIR) nitrile (NBR) rubbers. Mechanical properties the were correlated against composition. Although hardness tensile strength increase increasing content for all blends, elongation at break values initially decrease then in range 20–40% thermoplastic. For various blend compositions, swelling behavior evaluated solvents that are able dissolve uncured rubber portion but not component mixtures. All five systems showed index substantially less than calculated “theoretical” index. This attributed a caging effect on phase, which restricts access solvent phase. In turn, this affects resistance blend. Some by differential scanning calorimetry assess compatibility components electron microscopy also determine degree two phases generated mixing process. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci,
polymerengineering.ca 参考文章(33)
Polypropylene : structure, blends and composites Springer Netherlands. ,(1995) , 10.1007/978-94-011-0521-7
J. D. (Jack) Van Dyke, Marek Gnatowski, Andy Koutsandreas, Andrew Burczyk, Effect of butyl rubber type on properties of polyamide and butyl rubber blends Journal of Applied Polymer Science. ,vol. 93, pp. 1423- 1435 ,(2004) , 10.1002/APP.20565
S R. C. Kumar, Sobha V. Nair, George, K. E., Oommen, Z., and Thomas, Blends of nylon/acrylonitrile butadiene rubber: Effects of blend ratio, dynamic vulcanization and reactive compatibilization on rheology and extrudate morphology Polymer Engineering and Science. ,vol. 43, pp. 1555- 1565 ,(2003) , 10.1002/PEN.10131
Jeroen Oderkerk, Gabriël Groeninckx, Morphology development by reactive compatibilisation and dynamic vulcanisation of nylon6/EPDM blends with a high rubber fraction Polymer. ,vol. 43, pp. 2219- 2228 ,(2002) , 10.1016/S0032-3861(01)00816-3
Soney C. George, K. N. Ninan, G. Geuskens, Sabu Thomas, Permeation of chlorinated hydrocarbons through nylon 6/ethylene–propylene rubber blends Journal of Applied Polymer Science. ,vol. 91, pp. 3756- 3764 ,(2004) , 10.1002/APP.13550
Martin van Duin, Recent Developments for EPDM‐Based Thermoplastic Vulcanisates Macromolecular Symposia. ,vol. 233, pp. 11- 16 ,(2006) , 10.1002/MASY.200690006
Xiangfu Zhang, Yong Zhang, Zonglin Peng, Xiuyong Shang, Yinxi Zhang, Dynamically vulcanized nitrile rubber/polyoxymethylene thermoplastic elastomers Journal of Applied Polymer Science. ,vol. 77, pp. 2641- 2645 ,(2000) , 10.1002/1097-4628(20000919)77:12<2641::AID-APP110>3.0.CO;2-0
Abhijit Jha, Anil K. Bhowmick, Influence of dynamic vulcanization and phase interaction on the swelling behavior of the thermoplastic elastomeric blends of nylon-6 and acrylate rubber in various solvents and oil Journal of Applied Polymer Science. ,vol. 69, pp. 2331- 2340 ,(1998) , 10.1002/(SICI)1097-4628(19980919)69:12<2331::AID-APP4>3.0.CO;2-9
J. D. (Jack) Van Dyke, Marek Gnatowski, Andy Koutsandreas, Andrew Burczyk, Scott Duncan, Chemical interaction in blends of polyamide and butyl rubbers Journal of Applied Polymer Science. ,vol. 89, pp. 980- 991 ,(2003) , 10.1002/APP.12232
S. Mishra, M. Hazarika, R. Chandra, Rheological Studies of Dynamic Vulcanization of Butyl Rubber and Polypropylene Blends Polymer-plastics Technology and Engineering. ,vol. 38, pp. 305- 310 ,(1999) , 10.1080/03602559909351579