Tritium permeation through clean incoloy 800 and sanicro 31 alloys and through steam oxidized incoloy 800

作者: J. T. Bell , J. D. Redman , H. P. Bittner

DOI: 10.1007/BF02661206

关键词: MetallurgyTritiumTemperature cyclingSurface oxidationElectroplated nickelPermeationIncoloyThermal shockMaterials scienceOxideNuclear chemistry

摘要: The tritium permeabilities,DK, of Incoloy 800 and Sanicro 31 have been determined for tube samples that were protected from surface oxidation by electroplated nickel. permeabilities these analogous alloys over the 400 to 750°C range essentially equal;DK = 0.566 exp (-16120/RT) 0.367 (-15610/RT cm3(T2 · STP) mm/(cmsu2 min torr1/2), respectively. effects ofin-situ steam observed reduce factors up at 150 days. Permeation rates through oxide-coated be 0.5 rather than 1.0 power dependent on pressure. Permeabilities oxides formed 520, 660 725°C 5.4 E-11, 4.9 E-10 2.4 E-9 cc (T2,STP) mm/(cm2 Severe thermal shock was destroy permeation barrier characteristics oxide coatings while mild temperature cycling had no observable coated material.

参考文章(11)
H. F. Bittner, J. T. Bell, J. D. Redman, W. H. Christie, R. E. Eby, Analysis of oxide coatings on steam-oxidized Incoloy 800 Metallurgical and Materials Transactions A-physical Metallurgy and Materials Science. ,vol. 11, pp. 783- 790 ,(1980) , 10.1007/BF02661207
H.D. Röhrig, R. Hecker, J. Blumensaat, J. Schaefer, Studies on the permeation of hydrogen and tritium in nuclear process heat installations Nuclear Engineering and Design. ,vol. 34, pp. 157- 167 ,(1975) , 10.1016/0029-5493(75)90164-8
J. T. Bell, J. D. Redman, Permeation of hydrogen isotopes in nickel The Journal of Physical Chemistry. ,vol. 82, pp. 2834- 2838 ,(1978) , 10.1021/J100515A018
Saul Dushman, J. R. Pierce, Scientific foundations of vacuum technique ,(1949)
W.A. Swansiger, R.G. Musket, L.J. Weirick, W. Bauer, Deuterium permeation through 309S stainless steel with thin, characterized oxides Journal of Nuclear Materials. ,vol. 53, pp. 307- 312 ,(1974) , 10.1016/0022-3115(74)90262-1
D. R. Begeal, The permeation and diffusion of hydrogen and deuterium through Rodar, tin−coated Rodar, and solder−coated Rodar Journal of Vacuum Science and Technology. ,vol. 12, pp. 405- 409 ,(1975) , 10.1116/1.568586
Nelson W. Taylor, William Rast, The Diffusion of Helium and of Hydrogen Through Pyrex Chemically Resistant Glass The Journal of Chemical Physics. ,vol. 6, pp. 612- 619 ,(1938) , 10.1063/1.1750133
E.H. Van Deventer, T.A. Renner, R.H. Pelto, V.A. Maroni, Effects of surface impurity layers on the hydrogen permeability of vanadium Journal of Nuclear Materials. ,vol. 64, pp. 241- 248 ,(1977) , 10.1016/0022-3115(77)90075-7