Reactor Studies of Supported Ionic Liquids: Rhodium-catalysed Hydrogenation of Propene
作者： K. Scott , N. Basov , R.J.J. Jachuck , N. Winterton , A. Cooper
DOI: 10.1205/CHERD.04303
关键词: Chemistry 、 Thin layers 、 Catalysis 、 Membrane reactor 、 Propane 、 Organic chemistry 、 Rhodium 、 Chemical engineering 、 Propene 、 Polymer 、 Ionic liquid
摘要: Rhodium-based catalysts in ionic liquids have been used for the hydrogenation of propene a reactor composed thin layers catalyst solution supported on or corrugated polymer sheets operated cross-corrugated configuration. The effect number and reactant gas flow rate is described. Conversions to propane up 95% demonstrated performance has maintained over hundreds hours operation. catalyst-membrane system based rhodium(I)-[bmim]PF6-PESC was found be remarkably robust, retaining high levels activity after removal from reactor, storage air 3 months re-introduction into reactor.
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