Reactions of H2 with the Nickel Site(s) of the [FeNi] and [FeNiSe] Hydrogenases: What Do the Model Complexes Suggest?
作者： Christine Marganian Goldman , Pradip K. Mascharak
DOI: 10.1080/02603599508033861
关键词: Computational chemistry 、 Nickel 、 Hydrogenase 、 Chemistry 、 Active site 、 Organic chemistry 、 Structure and function
摘要: Abstract In recent years, the structure(s) of active site(s) nickel-containing hydrogenases (H2ases) and mode H2 activation at nickel these enzymes have been explored in detail. such pursuit, spectroscopic kinetic measurements performed on several H2ases. Despite all data, mechanism(s) assimilation evolution by microorganisms remain rather elusive present time. Several groups, including ours, therefore adopted modeling approach to elucidate structure function biological site. This review contains a concise account experiments as background for subsequent studies. It also provides comprehensive summary work our group others. Specific attempts made correlate spectral reactivity parameters good model complexes with those H2ases derive conclusions regarding structural functional char...
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