Catalytic transfer hydrogenation in γ-valerolactone-based ionic liquids
作者： Andrea Strádi , Márk Molnár , Péter Szakál , Gábor Dibó , Dániel Gáspár
DOI: 10.1039/C5RA08297H
关键词: Ion 、 Catalysis 、 Organic chemistry 、 Chemistry 、 Acetophenone 、 Inorganic chemistry 、 Ionic liquid 、 Valerolactone 、 Hydrogen 、 Transfer hydrogenation 、 Transition metal
摘要: The combination of transfer hydrogenation reaction with the advantages γ-valerolactone-based ionic liquids could result in an environmentally benign method for reduction organic substrates. Ionic containing 4-hydroxyvalerate anion were applied as alternative solvents acetophenone, its substituted forms and different alkenes using transition metal based catalysts. optimal conditions (e.g. type catalyst precursor hydrogen donor) transformation also specified.
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sci-hub.se 参考文章(49)
Welton Tom, P Hallett Jason, 室温イオン液体 合成溶媒および触媒反応 2 Chemical Reviews. ,vol. 111, pp. 3508- 3576 ,(2011)
Claire Comyns, Nazira Karodia, Serge Zeler, Jo‐Ann Andersen, Clean catalysis with clean solvents : phosphonium tosylates for transfer hydrogenation reactions Catalysis Letters. ,vol. 67, pp. 113- 115 ,(2000) , 10.1023/A:1019005202912
Ferenc Joó, Aqueous organometallic catalysis ,(2001)
Paul T. Anastas, John Charles Warner, Green Chemistry: Theory and Practice ,(1998)
Viktória Fábos, Diána Lantos, Andrea Bodor, Ana-Maria Bálint, László T. Mika, Ot E. Sielcken, Agnes Cuiper, István T. Horváth, ε-caprolactamium hydrogen sulfate: An ionic liquid used for decades in the large-scale production of ε-caprolactam Chemsuschem. ,vol. 1, pp. 189- 192 ,(2008) , 10.1002/CSSC.200700135
Tilmann J. Geldbach, Paul J. Dyson, A Versatile Ruthenium Precursor for Biphasic Catalysis and Its Application in Ionic Liquid Biphasic Transfer Hydrogenation: Conventional vs Task-Specific Catalysts Journal of the American Chemical Society. ,vol. 126, pp. 8114- 8115 ,(2004) , 10.1021/JA048886K
Szilárd Csihony, Hasan Mehdi, István T. Horváth, In situ infrared spectroscopic studies of theFriedel–Crafts acetylation of benzene in ionic liquids usingAlCl3 and FeCl3 Green Chemistry. ,vol. 3, pp. 307- 309 ,(2001) , 10.1039/B107515M
Dániel Fegyverneki, László Orha, Győző Láng, István T Horváth, None, Gamma-valerolactone-based solvents Tetrahedron. ,vol. 66, pp. 1078- 1081 ,(2010) , 10.1016/J.TET.2009.11.013
Attila Bényei, Ferenc Joó, None, Organometallic catalysis in aqueous solutions: the biphasic transfer hydrogenation of aldehydes catalyzed by water-soluble phosphine complexes of ruthenium, rhodium and iridium Journal of Molecular Catalysis. ,vol. 58, pp. 151- 163 ,(1990) , 10.1016/0304-5102(90)85035-G
Asit K. Chakraborti, Sudipta Raha Roy, On Catalysis by Ionic Liquids Journal of the American Chemical Society. ,vol. 131, pp. 6902- 6903 ,(2009) , 10.1021/JA900076A