Asymmetric Reduction of Ketones to Chiral Platform Molecules
作者： Bálint Fridrich , József M. Tukacs , László T. Mika
DOI: 10.1016/B978-0-12-812824-4.00012-5
关键词:
摘要: The enantioselective reduction of prochiral substrates including C=O double bonds is fundamentally important in the synthesis biologically active compounds. Due to depletion fossil-based resources, production these species from renewable resources highly desired. enantiopure γ-valerolactone was proposed as a biomass-based chiral platform molecule that can be easily obtained by asymmetric levulinic acid and its esters. Synthetic schemes optically are presented. effect catalyst composition reaction parameters on activity selectivity will discussed detail.
sci-hub.se 参考文章(74)
K. Mori, Synthesis of optically active forms of sulcatol Tetrahedron. ,vol. 31, pp. 3011- 3012 ,(1975) , 10.1016/0040-4020(75)80138-4
Viktória Fábos, Matthew Y. Lui, Yiu Fung Mui, Yuet Yan Wong, László T. Mika, Long Qi, Edit Cséfalvay, Viktória Kovács, Tibor Szűcs, István T. Horváth, Use of Gamma-Valerolactone as an Illuminating Liquid and Lighter Fluid ACS Sustainable Chemistry & Engineering. ,vol. 3, pp. 1899- 1904 ,(2015) , 10.1021/ACSSUSCHEMENG.5B00465
József M. Tukacs, Bálint Fridrich, Gábor Dibó, Edit Székely, László T. Mika, Direct asymmetric reduction of levulinic acid to gamma-valerolactone: synthesis of a chiral platform molecule Green Chemistry. ,vol. 17, pp. 5189- 5195 ,(2015) , 10.1039/C5GC01099C
Péter Pongrácz, László Kollár, László T. Mika, A step towards hydroformylation under sustainable conditions: platinum-catalysed enantioselective hydroformylation of styrene in gamma-valerolactone Green Chemistry. ,vol. 18, pp. 842- 847 ,(2016) , 10.1039/C5GC01778E
Andrea Strádi, Márk Molnár, Péter Szakál, Gábor Dibó, Dániel Gáspár, László T Mika, None, Catalytic transfer hydrogenation in γ-valerolactone-based ionic liquids RSC Advances. ,vol. 5, pp. 72529- 72535 ,(2015) , 10.1039/C5RA08297H
Ruth Patchett, Iris Magpantay, Lionel Saudan, Christoph Schotes, Antonio Mezzetti, Francesco Santoro, Asymmetric Hydrogenation of Ketones with H2 and Ruthenium Catalysts Containing Chiral Tetradentate S2N2 Ligands Angewandte Chemie. ,vol. 52, pp. 10352- 10355 ,(2013) , 10.1002/ANIE.201304844
Hideo Shimizu, Izuru Nagasaki, Kazuhiko Matsumura, Noboru Sayo, Takao Saito, Developments in Asymmetric Hydrogenation from an Industrial Perspective Accounts of Chemical Research. ,vol. 40, pp. 1385- 1393 ,(2007) , 10.1021/AR700101X
Ármin Szabolcs, Márk Molnár, Gábor Dibó, László T. Mika, Microwave-assisted conversion of carbohydrates to levulinic acid: an essential step in biomass conversion Green Chemistry. ,vol. 15, pp. 439- 445 ,(2013) , 10.1039/C2GC36682G
Anna Maria Raspolli Galletti, Claudia Antonetti, Erika Ribechini, Maria Perla Colombini, Nicoletta Nassi o Di Nasso, Enrico Bonari, From giant reed to levulinic acid and gamma-valerolactone: A high yield catalytic route to valeric biofuels Applied Energy. ,vol. 102, pp. 157- 162 ,(2013) , 10.1016/J.APENERGY.2012.05.061
Viktória Fábos, Gabriella Koczó, Hasan Mehdi, László Boda, István T. Horváth, Bio-oxygenates and the peroxide number: a safety issue alert Energy and Environmental Science. ,vol. 2, pp. 767- 769 ,(2009) , 10.1039/B900229B