Input power dependence of growth rate and quality of diamond films deposited in a d.c. arcjet system

作者: W.Z. Tang , G.F. Zhong , F.Z. Shen , F.X. Lu

DOI: 10.1016/S0925-9635(98)00300-8

关键词: CarbonDiamondArcjet rocketOptoelectronicsGrowth rateCarbon filmNanotechnologyHydrogenMaterials sciencePlasma torchChemical vapor deposition

摘要: Abstract Using a d.c. arcjet chemical vapor deposition (CVD) system, the dependence of growth rate and quality diamond films on input power to plasma torch was investigated. It found that in remote methane feed mode, increases as increases, confirming benefit using high torches. But unexpectedly, content non-diamond carbon or defect density thin increase function power, thick film deposited at low quality. These results were analyzed considering kinetics gas activation taking place CVD process. is believed along with atomic hydrogen will effectively activate hydrocarbon radicals, which bring about both large probability incorporation into growing materials.

参考文章(6)
Michael H. Loh, Mark A. Cappelli, CH3 detection in a low-density supersonic arcjet plasma during diamond synthesis Applied Physics Letters. ,vol. 70, pp. 1052- 1054 ,(1997) , 10.1063/1.118439
Scott W. Reeve, Wayne A. Weimer, Optimizing the gas phase chemistry in a d.c. arcjet diamond chemical vapor deposition reactor Thin Solid Films. ,vol. 253, pp. 103- 108 ,(1994) , 10.1016/0040-6090(94)90302-6
James A. Miller, Craig T. Bowman, Mechanism and modeling of nitrogen chemistry in combustion Progress in Energy and Combustion Science. ,vol. 15, pp. 287- 338 ,(1989) , 10.1016/0360-1285(89)90017-8
W. L. Gardner, Determination of diamond growth rate in a flow tube geometry as a function of measured atomic hydrogen density Journal of Vacuum Science and Technology. ,vol. 14, pp. 1938- 1942 ,(1996) , 10.1116/1.580364
D. G. Goodwin, Scaling laws for diamond chemical‐vapor deposition. I. Diamond surface chemistry Journal of Applied Physics. ,vol. 74, pp. 6888- 6894 ,(1993) , 10.1063/1.355063
L. Robbin Martin, Diamond film growth in a flowtube: A temperature dependence study Journal of Applied Physics. ,vol. 70, pp. 5667- 5674 ,(1991) , 10.1063/1.350183