Catalytic Organic Transformations Mediated by Actinide Complexes
作者： Isabell Karmel , Rami Batrice , Moris Eisen
DOI: 10.3390/INORGANICS3040392
关键词: Hydroalkoxylation 、 Actinide 、 Hydrosilylation 、 Hydroamination 、 Ring-opening polymerization 、 Catalysis 、 Polymerization 、 Organic chemistry 、 Homogeneous catalysis 、 Combinatorial chemistry 、 Chemistry
摘要: This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. chapter introduces basic principles catalysis deals with historic in catalytic processes. The application is exemplified hydroelementation reactions, such hydroamination, hydrosilylation, hydroalkoxylation hydrothiolation alkynes. Additionally, use polymerization α-olefins ring opening cyclic esters presented. last part this highlights novel transformations mediated by compounds gives an outlook to further potential field.
mdpi.com
core.ac.uk 
sci-hub.se 参考文章(110)
Fengyu Bao, Ken-ichiro Kanno, Tamotsu Takahashi, ChemInform Abstract: Early Transition Metal Catalyzed Hydrosilation Reaction ChemInform. ,vol. 41, pp. no- no ,(2010) , 10.1002/CHIN.201023225
T. J. Marks, M. R. Gagne, S. P. Nolan, L. E. Schock, A. M. Seyam, D. Stern, What can metal-ligand bonding energetics teach us about stoichiometric and catalytic organometallic chemistry? Pure and Applied Chemistry. ,vol. 61, pp. 1665- 1672 ,(1989) , 10.1351/PAC198961101665
Michel Ephritikhine, Recent Advances in Organoactinide Chemistry As Exemplified by Cyclopentadienyl Compounds Organometallics. ,vol. 32, pp. 2464- 2488 ,(2013) , 10.1021/OM400145P
Gabriele Lugli, Alessandro Mazzei, Sergio Poggio, High 1,4‐cis‐polybutadiene by uranium catalysts, 1. Tris(π‐allyl)uranium halide catalysts Macromolecular Chemistry and Physics. ,vol. 175, pp. 2021- 2027 ,(1974) , 10.1002/MACP.1974.021750706
Mark David Greenhalgh, Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes ,(2016)
Jiaxi Wang, Aswini Kumar Dash, Moshe Kapon, Jean-Claude Berthet, Michel Ephritikhine, Moris S. Eisen, Oligomerization and hydroamination of terminal alkynes promoted by the cationic organoactinide compound [(Et2N)3U][BPh4]. Chemistry: A European Journal. ,vol. 8, pp. 5384- 5396 ,(2002) , 10.1002/1521-3765(20021202)8:23<5384::AID-CHEM5384>3.0.CO;2-X
Zhu Du, Hui Zhou, Haisheng Yao, Yong Zhang, Yingming Yao, Qi Shen, The first bridged lanthanide carbene complex formed through reduction of carbodiimide by diamine-bis(phenolate) ytterbium(II) complex and its reactivity to phenylisocyanate. Chemical Communications. ,vol. 47, pp. 3595- 3597 ,(2011) , 10.1039/C0CC04504G
Azusa Kondoh, Kazuaki Takami, Hideki Yorimitsu, Koichiro Oshima, Stereoselective hydrothiolation of alkynes catalyzed by cesium base: Facile access to (Z)-1-alkenyl sulfides Journal of Organic Chemistry. ,vol. 70, pp. 6468- 6473 ,(2005) , 10.1021/JO050931Z
Charles J. Weiss, Stephen D. Wobser, Tobin J. Marks, Lanthanide- and actinide-mediated terminal alkyne hydrothiolation for the catalytic synthesis of markovnikov vinyl sulfides Organometallics. ,vol. 29, pp. 6308- 6320 ,(2010) , 10.1021/OM100697H
Cassandra E. Hayes, Yann Sarazin, Michael J. Katz, Jean-François Carpentier, Daniel B. Leznoff, Diamido-Ether Actinide Complexes as Initiators for Lactide Ring-Opening Polymerization Organometallics. ,vol. 32, pp. 1183- 1192 ,(2013) , 10.1021/OM300993R