Organoactinide‐Catalyzed Monohydroboration of Carbodiimides

作者: Heng Liu , Kseniya Kulbitski , Matthias Tamm , Moris S. Eisen

DOI: 10.1002/CHEM.201705987

关键词:

摘要: The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. catalytic reactions proceed under very mild conditions in a highly atom-efficient and selective fashion to afford the corresponding monohydroborated N-borylformamidine products high yields. A plausible mechanism proposed based on stoichiometric kinetic studies.

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