Fabrication of isotype (p-p) selenium–polyaniline heterojunction diode by electrochemical method

作者: S.S. Joshi , C.D. Lokhande

DOI: 10.1016/J.APSUSC.2005.11.070

关键词: PolyanilineSeleniumAnalytical chemistryCurrent densityHeterojunctionMonoclinic crystal systemDiodeAmorphous solidThin filmMaterials science

摘要: Abstract In the present work, for first time, heterojunction has been fabricated using electrochemically deposited isotype p-selenium–p-polyaniline from a single solution bath. The structural characterization of selenium and polyaniline thin film was carried out XRD technique. Polyaniline exhibited amorphous structure while offered monoclinic ( β ) phase. junction formed by electrodepositing over heating at 423 K. current density versus voltage J – V plot showed formation with ideality factor 1.16. From characteristics different temperatures, static resistance R s ), dynamic d rectification ratio diodes were determined. Heat treatment above 448 K caused breakdown.

参考文章(16)
H. Nguyen Cong, C. Sene, P. Chartier, Poly(3-methylthiophene) structural change effect on characteristics of CdS(A1):PMeT photovoltaic junction Solar Energy Materials and Solar Cells. ,vol. 40, pp. 261- 271 ,(1996) , 10.1016/0927-0248(95)00093-3
G Hema Chandra, O.M Hussain, S Uthanna, B Srinivasulu Naidu, Photovoltaic performance of p-AgGa0.25In0.75Se2/n-CdS thin film heterojunctions Materials Letters. ,vol. 53, pp. 216- 220 ,(2002) , 10.1016/S0167-577X(01)00479-7
H. Nguyen Cong, C. Sene, P. Chartier, Photovoltaic cell based on cadmium sulfide sprayed film and electrolytic poly(3-methylthiophene): Solvent nature effect Solar Energy Materials and Solar Cells. ,vol. 30, pp. 127- 138 ,(1993) , 10.1016/0927-0248(93)90014-T
B. Xu, Y. Ovchenkov, M. Bai, A. N. Caruso, A. V. Sorokin, Stephen Ducharme, B. Doudin, P. A. Dowben, Heterojunction diode fabrication from polyaniline and a ferroelectric polymer Applied Physics Letters. ,vol. 81, pp. 4281- 4283 ,(2002) , 10.1063/1.1524695
P. Syed Abthagir, R. Saraswathi, Rectifying properties of poly(N-methylaniline) Journal of Materials Science: Materials in Electronics. ,vol. 15, pp. 81- 86 ,(2004) , 10.1023/B:JMSE.0000005380.59176.C1
S.A. Gamboa, H. Nguyen-Cong, P. Chartier, P.J. Sebastian, M.E. Calixto, M.A. Rivera, Photovoltaic structures based on polymer/semiconductor junctions Solar Energy Materials and Solar Cells. ,vol. 55, pp. 95- 104 ,(1998) , 10.1016/S0927-0248(98)00050-6
W.G. Oldham, A.G. Milnes, n-n Semiconductor heterojunctions Solid-State Electronics. ,vol. 6, pp. 121- 132 ,(1963) , 10.1016/0038-1101(63)90005-4
R. Murugesan, E. Subramanian, Metal oxalate complexes as novel inorganic dopants: Studies on their effect on conducting polyaniline Bulletin of Materials Science. ,vol. 25, pp. 613- 618 ,(2002) , 10.1007/BF02707894
H. Nguyen Cong, C. Sene, P. Chartier, Cadmium sulfide thickness effect on the photoresponse of the CdS(A1) spray/poly(3-methylthiophene) solid state junction Solar Energy Materials and Solar Cells. ,vol. 29, pp. 209- 219 ,(1993) , 10.1016/0927-0248(93)90036-3
A. E. Rakhshani, Heterojunction properties of electrodeposited CdTe/CdS solar cells Journal of Applied Physics. ,vol. 90, pp. 4265- 4271 ,(2001) , 10.1063/1.1397279