Effects of confinement on the Rydberg molecule NeH
作者： J M H Lo , M Klobukowski , D Bielińska-Wa̧ż , G H F Diercksen , E W S Schreiner
DOI: 10.1088/0953-4075/38/8/006
关键词: Autoionization 、 Physics 、 Rydberg formula 、 Ab initio quantum chemistry methods 、 Ionization 、 Configuration interaction 、 Excited state 、 Rydberg molecule 、 Atomic physics 、 Ab initio 、 Atomic and Molecular Physics, and Optics 、 Condensed matter physics
摘要: Ab initio potential energy curves of the Rydberg NeH molecule in presence cylindrical spatial confinement were computed by method multi-reference configuration interaction with extended basis sets. The influence applied to structures and spectra ground excited states was analysed terms perturbation theory. In addition, phenomenon field-induced ionization discussed.
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