Deep eutectic solvents: syntheses, properties and applications

作者: Qinghua Zhang , Karine De Oliveira Vigier , Sébastien Royer , François Jérôme

DOI: 10.1039/C2CS35178A

关键词: Ionic liquidGreen chemistryOrganic synthesisFlammabilityDeep eutectic solventEutectic systemDissolutionChemistryNanotechnologyIonic bonding

摘要: Within the framework of green chemistry, solvents occupy a strategic place. To be qualified as medium, these have to meet different criteria such availability, non-toxicity, biodegradability, recyclability, flammability, and low price among others. Up now, number available are rather limited. Here we wish discuss new family ionic fluids, so-called Deep Eutectic Solvents (DES), that now rapidly emerging in current literature. A DES is fluid generally composed two or three cheap safe components capable self-association, often through hydrogen bond interactions, form eutectic mixture with melting point lower than each individual component. DESs liquid at temperatures 100 °C. These exhibit similar physico-chemical properties traditionally used liquids, while being much cheaper environmentally friendlier. Owing remarkable advantages, growing interest many fields research. In this review, report major contributions catalysis, organic synthesis, dissolution extraction processes, electrochemistry material chemistry. All works discussed review aim demonstrating not only allow design eco-efficient processes but also open straightforward access chemicals materials.

参考文章(191)
William T.A. Harrison, C5H14NO · ZnCl(HPO3), an unexpected product from an ionic-liquid synthesis Inorganic Chemistry Communications. ,vol. 10, pp. 833- 835 ,(2007) , 10.1016/J.INOCHE.2007.04.010
L. Cammarata, S. G. Kazarian, P. A. Salter, T. Welton, Molecular states of water in room temperature ionic liquidsElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b106900d/ Physical Chemistry Chemical Physics. ,vol. 3, pp. 5192- 5200 ,(2001) , 10.1039/B106900D
Rong Wang, Takeyoshi Okajima, Fusao Kitamura, Takeo Ohsaka, A Novel Amperometric O2 Gas Sensor Based on Supported Room‐Temperature Ionic Liquid Porous Polyethylene Membrane‐Coated Electrodes Electroanalysis. ,vol. 16, pp. 66- 72 ,(2004) , 10.1002/ELAN.200302919
Joan Fuller, Richard T. Carlin, Robert A. Osteryoung, The room temperature ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate : Electrochemical couples and physical properties Journal of The Electrochemical Society. ,vol. 144, pp. 3881- 3886 ,(1997) , 10.1149/1.1838106
María C. Gutiérrez, Fausto Rubio, Francisco del Monte, Resorcinol-Formaldehyde Polycondensation in Deep Eutectic Solvents for the Preparation of Carbons and Carbon−Carbon Nanotube Composites Chemistry of Materials. ,vol. 22, pp. 2711- 2719 ,(2010) , 10.1021/CM9023502
Andrew P. Abbott, Gero Frisch, Jennifer Hartley, Karl S. Ryder, Processing of metals and metal oxides using ionic liquids Green Chemistry. ,vol. 13, pp. 471- 481 ,(2011) , 10.1039/C0GC00716A
Katherine D. Weaver, Hye Jin Kim, Jiazeng Sun, Douglas R. MacFarlane, Gloria D. Elliott, Cyto-toxicity and biocompatibility of a family of choline phosphate ionic liquids designed for pharmaceutical applications Green Chemistry. ,vol. 12, pp. 507- 513 ,(2010) , 10.1039/B918726J
K. Shahbaz, Farouq. S. Mjalli, M.A. Hashim, Inas. M. ALNashef, Using deep eutectic solvents for the removal of glycerol from palm oil-based biodiesel. Journal of Applied Sciences. ,vol. 10, pp. 3349- 3354 ,(2010) , 10.3923/JAS.2010.3349.3354
Andrew P. Abbott, Robert C. Harris, Karl S. Ryder, Application of hole theory to define ionic liquids by their transport properties. Journal of Physical Chemistry B. ,vol. 111, pp. 4910- 4913 ,(2007) , 10.1021/JP0671998
Mario G. Del Pópolo, Jorge Kohanoff, Ruth M. Lynden-Bell, Solvation structure and transport of acidic protons in ionic liquids: a first-principles simulation study. Journal of Physical Chemistry B. ,vol. 110, pp. 8798- 8803 ,(2006) , 10.1021/JP0602326