Air-foamed calcium aluminate phosphate cement for geothermal wells

作者: T. Sugama , L.E. Brothers , T.R. Van de Putte

DOI: 10.1016/J.CEMCONCOMP.2004.11.003

关键词: ReagentCarbon steelCementMaterials scienceCompressive strengthComposite materialSlurryCorrosionPorosityAluminate

摘要: Abstract Air-foamed low-density calcium aluminate phosphate (CaP) cement slurry was prepared by mixing it with chemical foaming reagent at room temperature without any pressure, followed autoclaving 200 °C. When the porosity, compressive strength, and water permeability of autoclaved CaP foam made from a 1.22 g/cc density compared those N2 gas-foamed Class G similar under high pressure hydrothermal 288 °C, revealed some advanced properties, such as higher strength lower porosity. These properties were due to hybrid formation three crystalline reaction products; hydroxyapatite, boehmite, hydrogarnet phases. However, one shortcoming an increase in because undesirable continuous porous structure caused coalesced air bubble cells, suggesting that appropriate lesser amount be used create conformation which fine discrete air-bubble cells are uniformly dispersed throughout slurry. For non-foamed cement, major factors contributed protecting carbon steel against corrosion: (1) good adherence steel, reflecting extent coverage layer over steel’s surfaces; (2) retardation cathodic corrosion reactions; and, (3) minimum conductivity corrosive ionic electrolytes. adding excessive did not offer effective protection cement.

参考文章(16)
R. Montman, B.G. Mody, W.M. Harms, D.L. Sutton, Low-density foamed Portland cements fill variety of needs Oil & Gas Journal. ,(1982)
M. Stern, A. L. Geaby, Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves Journal of The Electrochemical Society. ,vol. 104, pp. 56- 63 ,(1957) , 10.1149/1.2428496
Toshifumi Sugama, E. Wetzel, Microsphere-filled lightweight calcium phosphate cements Journal of Materials Science. ,vol. 29, pp. 5165- 5176 ,(1994) , 10.1007/BF01151112
George C. Hoff, Porosity-strength considerations for cellular concrete Cement and Concrete Research. ,vol. 2, pp. 91- 100 ,(1972) , 10.1016/0008-8846(72)90026-9
M.P. Bozich, R.C. Montman, W.M. Harms, Application of Foamed Portland Cement to Deep Well Conditions in West Texas SPE Deep Drilling and Production Symposium. ,(1984) , 10.2118/12612-MS
Olivier Poupard, Abdelkarim Aı̈t-Mokhtar, Paul Dumargue, Corrosion by chlorides in reinforced concrete: Determination of chloride concentration threshold by impedance spectroscopy Cement and Concrete Research. ,vol. 34, pp. 991- 1000 ,(2004) , 10.1016/J.CEMCONRES.2003.11.009
Rasto Brezny, David J. Green, Factors Controlling the Fracture Resistance of Brittle Cellular Materials Journal of the American Ceramic Society. ,vol. 74, pp. 1061- 1065 ,(1991) , 10.1111/J.1151-2916.1991.TB04343.X
T. D. Tonyan, L. J. Gibson, STRUCTURE AND MECHANICS OF CEMENT FOAMS Journal of Materials Science. ,vol. 27, pp. 6371- 6378 ,(1992) , 10.1007/BF00576287
Bruce J. Christensen, Thomas O. Mason, Hamlin M. Jennings, Influence of Silica Fume on the Early Hydration of Portland Cements Using Impedance Spectroscopy Journal of the American Ceramic Society. ,vol. 75, pp. 939- 945 ,(1992) , 10.1111/J.1151-2916.1992.TB04163.X
F. Mansfeld, M. W. Kendig, S. Tsai, Evaluation of Corrosion Behavior of Coated Metals with AC Impedance Measurements Corrosion. ,vol. 38, pp. 478- 485 ,(1982) , 10.5006/1.3577363