Membranes for direct methanol fuel cell based on modified heteropolyacids
作者： M.L Ponce , L.A.S de A. Prado , V Silva , S.P Nunes
DOI: 10.1016/S0011-9164(04)00072-4
关键词: Oxide 、 Polyether ether ketone 、 Inorganic chemistry 、 Chemistry 、 Membrane 、 Dispersion (chemistry) 、 Covalent bond 、 Direct methanol fuel cell 、 Silanes 、 Fumed silica 、 Mechanical engineering 、 General Materials Science 、 General chemistry 、 General Chemical Engineering 、 Water Science and Technology
摘要: Abstract Organic-inorganic membranes for direct methanol fuel cell (DMFC) application were prepared from sulfonated polyether ether ketone (SPEEK), containing heteropolyacids and an oxide phase either generated by hydrolysis ofamino-modified silanes or dispersion of a surface-modified fumed silica. The heteropolyacid was based on lacunary divacant [γ-SiW10O36]−8 contained epoxy groups which reacted with the ammo-groups in phase. reaction provides covalent bond between to insoluble phase, resulting its fixation membrane. organic-inorganic composites this way more stable than plain membrane, had lower crossover proton-conductivity same order magnitude.
elsevier.com
sci-hub.se 参考文章(20)
Michael Thor Pope, Heteropoly and isopoly oxometalates Inorganic chemistry concepts. ,vol. 8, ,(1983) , 10.1007/978-3-662-12004-0
Osamu Nakamura, Teruo Kodama, Isao Ogino, Yoshizo Miyake, High-conductivity solid proton conductors: Dodecamolybdophosphoric acid and dodecatungstophosphoric acid crystals. Chemistry Letters. ,vol. 8, pp. 17- 18 ,(1979) , 10.1246/CL.1979.17
G Alberti, M Casciola, L Massinelli, B Bauer, Polymeric proton conducting membranes for medium temperature fuel cells (110–160°C) Journal of Membrane Science. ,vol. 185, pp. 73- 81 ,(2001) , 10.1016/S0376-7388(00)00635-9
Cédric R. Mayer, Isabelle Fournier, René Thouvenot, Bis- and Tetrakis(organosilyl) Decatungstosilicate, [γ-SiW10O36(RSi)2O]4− and [γ-SiW10O36(RSiO)4]4−: Synthesis and Structural Determination by Multinuclear NMR Spectroscopy and Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry Chemistry: A European Journal. ,vol. 6, pp. 105- 110 ,(2000) , 10.1002/(SICI)1521-3765(20000103)6:1<105::AID-CHEM105>3.0.CO;2-L
B Tazi, O Savadogo, Parameters of PEM fuel-cells based on new membranes fabricated from Nafion®, silicotungstic acid and thiophene Electrochimica Acta. ,vol. 45, pp. 4329- 4339 ,(2000) , 10.1016/S0013-4686(00)00536-3
P Staiti, S Freni, S Hocevar, Synthesis and characterization of proton-conducting materials containing dodecatungstophosphoric and dodecatungstosilic acid supported on silica Journal of Power Sources. ,vol. 79, pp. 250- 255 ,(1999) , 10.1016/S0378-7753(99)00177-9
Masahiko Kamada, Hiroshi Kominami, Yoshiya Kera, Deposition and Interaction of Phosphododecatungstate on a Silica Gel Surface Modified with a Silane Coupling Agent Having Anilino Groups joint international conference on information sciences. ,vol. 182, pp. 297- 300 ,(1996) , 10.1006/JCIS.1996.0464
P Dimitrova, KA Friedrich, U Stimming, B Vogt, Modified Nafion®-based membranes for use in direct methanol fuel cells Solid State Ionics. ,vol. 150, pp. 115- 122 ,(2002) , 10.1016/S0167-2738(02)00267-9
Zen-ichi Yoshida, Shigeo Yoneda, Toyonari Sugimoto, THIOPYRYLIUM ION AS AN ELECTRON ACCEPTOR IN CHARGE-TRANSFER COMPLEX FORMATION Chemistry Letters. ,vol. 1, pp. 17- 20 ,(1972) , 10.1246/CL.1972.17
U Lavrenčič Štangar, N Grošelj, B Orel, A Schmitz, Ph Colomban, Proton-conducting sol-gel hybrids containing heteropoly acids Solid State Ionics. ,vol. 145, pp. 109- 118 ,(2001) , 10.1016/S0167-2738(01)00920-1