Room-Temperature Hydrogenation of Citral Catalyzed by Palladium–Silver Nanocrystals Supported on SnO2
作者： Shuo Wang , Rongan Shen , Zheng Chen , Jiaxi Wang , Dingsheng Wang
关键词: Palladium 、 Organic chemistry 、 Medicinal chemistry 、 Citral 、 Selectivity 、 Conjugated system 、 Citronellal 、 Metal 、 Chemistry 、 Catalysis 、 Heterogeneous catalysis
摘要: We have developed two strategies to optimize Pd catalysts. On one hand, Ag was introduced into and then they were applied the selective hydrogenation of citral under mild conditions. The addition metallic could tune selectivity made it suitable for conjugated double bond. citronellal increased from 0 (for Pd/C Pd0.7Ag0.3/C) 96 % Pd0.4Ag0.6/C) as content increased. other SnO2 catalysts more inclined activate C=O bond gave better performance compared with corresponding Pd–Ag 76 % Pd0.7Ag0.3–SnO2/C used) after SnO2. basis these results, we a catalyst (Pd0.6Ag0.4–SnO2/C) best catalytic (the conversion reached 99 %, up 96 %).
sci-hub.se 参考文章(31)
Daniel A. Slanac, William G. Hardin, Keith P. Johnston, Keith J. Stevenson, Atomic ensemble and electronic effects in Ag-rich AgPd nanoalloy catalysts for oxygen reduction in alkaline media Journal of the American Chemical Society. ,vol. 134, pp. 9812- 9819 ,(2012) , 10.1021/JA303580B
Eero Salminen, Pasi Virtanen, Krisztián Kordás, Jyri-Pekka Mikkola, Alkaline modifiers as performance boosters in citral hydrogenation over supported ionic liquid catalysts (SILCAs) Catalysis Today. ,vol. 196, pp. 126- 131 ,(2012) , 10.1016/J.CATTOD.2012.04.066
Aurélie Vicente, Gwendoline Lafaye, Catherine Especel, Patrice Marécot, Christopher T. Williams, The relationship between the structural properties of bimetallic Pd–Sn/SiO2 catalysts and their performance for selective citral hydrogenation Journal of Catalysis. ,vol. 283, pp. 133- 142 ,(2011) , 10.1016/J.JCAT.2011.07.010
A. Jung, A. Jess, T. Schubert, W. Schütz, Performance of carbon nanomaterial (nanotubes and nanofibres) supported platinum and palladium catalysts for the hydrogenation of cinnamaldehyde and of 1-octyne Applied Catalysis A-general. ,vol. 362, pp. 95- 105 ,(2009) , 10.1016/J.APCATA.2009.04.026
Nicole A. Dehm, Xiaojiang Zhang, Jillian M. Buriak, Screening of Bimetallic Heterogeneous Nanoparticle Catalysts for Arene Hydrogenation Activity under Ambient Conditions Inorganic Chemistry. ,vol. 49, pp. 2706- 2714 ,(2010) , 10.1021/IC901928J
Linsen Li, Zhiqiang Niu, Shuangfei Cai, Yun Zhi, Hao Li, Hongpan Rong, Lichen Liu, Lei Liu, Wei He, Yadong Li, A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes Chemical Communications. ,vol. 49, pp. 6843- 6845 ,(2013) , 10.1039/C3CC00249G
Nicolás M. Bertero, Andrés F. Trasarti, Bernard Moraweck, Armando Borgna, Alberto J. Marchi, Selective liquid-phase hydrogenation of citral over supported bimetallic Pt–Co catalysts Applied Catalysis A-general. ,vol. 358, pp. 32- 41 ,(2009) , 10.1016/J.APCATA.2009.01.036
Patricia A Robles-Dutenhefner, Marcelo G Speziali, Edésia MB Sousa, Eduardo N dos Santos, Elena V Gusevskaya, None, Selective hydrogenation of myrcene catalyzed by sol–gel Pd/SiO2 Applied Catalysis A-general. ,vol. 295, pp. 52- 58 ,(2005) , 10.1016/J.APCATA.2005.08.005
Achim Stolle, Thomas Gallert, Christine Schmöger, Bernd Ondruschka, Hydrogenation of citral: a wide-spread model reaction for selective reduction of α,β-unsaturated aldehydes RSC Advances. ,vol. 3, pp. 2112- 2153 ,(2013) , 10.1039/C2RA21498A
Christine Schmöger, Achim Stolle, Werner Bonrath, Bernd Ondruschka, Thomas Keller, Klaus D. Jandt, A practical approach for ambient-pressure hydrogenations using Pd on porous glass. Chemsuschem. ,vol. 2, pp. 77- 82 ,(2009) , 10.1002/CSSC.200800168