Carbon fiber embedded chitosan/PVA composites for decontamination of endocrine disruptor bisphenol-A from water
作者： Esra Bilgin Simsek , Didem Saloglu , Nazlı Ozcan , Ivan Novak , Dusan Berek
DOI: 10.1016/J.JTICE.2016.11.008
关键词: Composite material 、 Langmuir adsorption model 、 Composite number 、 Fourier transform infrared spectroscopy 、 Polymer 、 Bisphenol A 、 Materials science 、 Microporous material 、 Freundlich equation 、 Adsorption
摘要: Abstract Microporous carbon fibers (CFs) were in situ embedded chitosan‒polyvinyl alcohol (CHT-PVA) polymer matrix to produce an approximately 10 mm-thick carbon-polymer composite film (CHT-PVA/CF). The films prepared with different CF:(CHT-PVA) ratios of 0.5–3.0 (w/w) and used as novel adsorbents for the remediation bisphenol A (BPA) from water. composites characterized by SEM, TGA-DTG, FTIR XPS analysis. When CF was introduced into CHT-PVA, BPA removal performance increased 5.8% 97.6%. adsorption performances CHT-PVA/CF investigated respect solution pH, temperature time. optimal pH maximum found 6.0. Freundlich Dubinin–Raduskevich isotherm models fitted equilibrium data better than Langmuir model. According kinetics results, time 2 h kinetic well described pseudo-second-order equation. After saturated adsorption, can be easily regenerated reused within five cycles.
sci-hub.se 参考文章(39)
Dajian Huang, Bin Mu, Aiqin Wang, Preparation and properties of chitosan/poly (vinyl alcohol) nanocomposite films reinforced with rod-like sepiolite Materials Letters. ,vol. 86, pp. 69- 72 ,(2012) , 10.1016/J.MATLET.2012.07.020
Andreea Madalina Pandele, Mariana Ionita, Livia Crica, Sorina Dinescu, Marieta Costache, Horia Iovu, Synthesis, characterization, and in vitro studies of graphene oxide/chitosan–polyvinyl alcohol films Carbohydrate Polymers. ,vol. 102, pp. 813- 820 ,(2014) , 10.1016/J.CARBPOL.2013.10.085
Dianxun Hou, Ronn Goei, Xiaoping Wang, Penghua Wang, Teik-Thye Lim, Preparation of carbon-sensitized and Fe–Er codoped TiO2 with response surface methodology for bisphenol A photocatalytic degradation under visible-light irradiation Applied Catalysis B-environmental. ,vol. 126, pp. 121- 133 ,(2012) , 10.1016/J.APCATB.2012.07.012
Nabarun Roy, Rajatendu Sengupta, Anil K. Bhowmick, Modifications of carbon for polymer composites and nanocomposites Progress in Polymer Science. ,vol. 37, pp. 781- 819 ,(2012) , 10.1016/J.PROGPOLYMSCI.2012.02.002
Hua-Yue Zhu, Ru Jiang, Ling Xiao, Adsorption of an anionic azo dye by chitosan/kaolin/γ-Fe2O3 composites Applied Clay Science. ,vol. 48, pp. 522- 526 ,(2010) , 10.1016/J.CLAY.2010.02.003
Esra Bilgin Simsek, Ercan Özdemir, Ulker Beker, Zeolite supported mono- and bimetallic oxides: Promising adsorbents for removal of As(V) in aqueous solutions Chemical Engineering Journal. ,vol. 220, pp. 402- 411 ,(2013) , 10.1016/J.CEJ.2013.01.070
Iwona Wróbel-Iwaniec, Noel Díez, Grażyna Gryglewicz, Chitosan-based highly activated carbons for hydrogen storage International Journal of Hydrogen Energy. ,vol. 40, pp. 5788- 5796 ,(2015) , 10.1016/J.IJHYDENE.2015.03.034
Yan Liu, Shanli Yang, Weifen Niu, Simple, rapid and green one-step strategy to synthesis of graphene/carbon nanotubes/chitosan hybrid as solid-phase extraction for square-wave voltammetric detection of methyl parathion Colloids and Surfaces B: Biointerfaces. ,vol. 108, pp. 266- 270 ,(2013) , 10.1016/J.COLSURFB.2013.03.003
Michael J. Richardson, James H. Johnston, Sorption and binding of nanocrystalline gold by Merino wool fibres—An XPS study Journal of Colloid and Interface Science. ,vol. 310, pp. 425- 430 ,(2007) , 10.1016/J.JCIS.2007.01.075
Yuh-Shan Ho, Gordon McKay, Pseudo-second order model for sorption processes Process Biochemistry. ,vol. 34, pp. 451- 465 ,(1999) , 10.1016/S0032-9592(98)00112-5