Hydrogen Evolution from Water under Aerobic Conditions Catalyzed by a Cobalt ATCUN Metallopeptide
作者： Banu Kandemir , Lenore Kubie , Yixing Guo , Brian Sheldon , Kara L. Bren
DOI: 10.1021/ACS.INORGCHEM.5B02157
关键词: Tripeptide 、 Catalysis 、 Inorganic chemistry 、 Hydrogen 、 Nickel 、 Electrocatalyst 、 Chemistry 、 Copper 、 Cobalt 、 Faraday efficiency
摘要: The cobalt complex of an amino-terminal copper and nickel (ATCUN) motif model tripeptide (CoGGH) is shown to act as electrocatalyst for hydrogen evolution from water near neutral pH with high Faradaic efficiency. catalyst performance not significantly impacted by exposure oxygen. CoGGH represents a new class that straightforward prepare modify.
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