Enantioselective total syntheses of kudtriol, 5-epi-kudtriol and their C-11 epimers
作者： Gang Zhou , Xiaolei Gao , Zhe Zhang , Weidong Z Li , Yulin Li
DOI: 10.1016/S0957-4166(00)00119-1
关键词: Enantioselective synthesis 、 Stereochemistry 、 Absolute configuration 、 Sharpless asymmetric dihydroxylation 、 Epimer 、 Spectral data 、 Chemistry
摘要: Abstract Two approaches for the enantioselective syntheses of naturally occurring kudtriol 2a and 5- epi -kudtriol 3a as well their C-11 epimers are presented, both using Sharpless asymmetric dihydroxylation key reaction. Through comparison spectral data natural triols synthetic samples, we could confirm absolute configuration triols.
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