Synthesis and activity evaluation of heterometallic nano oxides integrated ZSM-5 catalysts for palm oil cracking to produce biogasoline
作者： Mushtaq Ahmad , Rafida Farhana , Abdul Aziz Abdul Raman , Suresh K. Bhargava
DOI: 10.1016/J.ENCONMAN.2016.04.069
关键词: Biogasoline 、 Fluid catalytic cracking 、 ZSM-5 、 Zeolite 、 Fourier transform infrared spectroscopy 、 Chemical engineering 、 Cracking 、 Nanotechnology 、 Biodiesel 、 Catalysis 、 Materials science
摘要: Biofuels produced from palm oil have shown great potential as a useful fossil fuel substitute and are environmental friendly. Utilization of biofuel requires zeolite based catalytic technology that facilitates selective conversion substrates to desired products, including biogasoline biodiesel. However, the synthesis integration suitable supported catalysts for products key challenges in production. The alternative overcome these problems is use nano heterometallic materials on catalysts. In this study, Zeolite Socony Mobile-5 (ZSM-5) loaded with oxides were synthesized. Next, used cracking produce characterized by field emission electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), high resolution transmission (HRTEM), Fourier transform infrared (FTIR) Brunauer, Emmett Teller (BET) analysis. Taguchi method was assess optimize process. results illustrated under optimized conditions, ZSM-5 (30), Fe-Zn-Cu-ZSM-5 (31), (32) Fe-Zn-ZSM-5 (33) yielded 14%, 59%, 49% 56% biogasoline, respectively. Higher efficiency (31) might be attributed higher content metal compared other synthesized yield catalyzed 8% more than literature values. Therefore, present study proved newly developed an efficient economical catalyst producing oil.
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