Columnar one-dimensional coordination polymer formed with a metal ion and a host–guest complex as building blocks: potassium ion complexed cucurbituril
作者： Jungseok Heo , Jaheon Kim , Dongmok Whang , Kimoon Kim
DOI: 10.1016/S0020-1693(99)00318-7
关键词: Inorganic chemistry 、 Supramolecular chemistry 、 Potassium 、 Ion 、 Molecule 、 Cucurbituril 、 Coordination polymer 、 Crystallography 、 Crystal engineering 、 Chemistry 、 Potassium ions
摘要: Abstract A novel one-dimensional coordination polymer comprising a metal ion and host–guest complex is described. Cucurbituril, barrel-shaped molecule potassium form columnar 1D in the solid state, formula of which [(C36H36N24O12)K2(OH)2·(C4H8O)]n. In polymer, cucurbituril molecules stack atop one another through their carbonyl groups to ions between. disordered THF encapsulated cavity each molecule.
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