Synthesis and crystal structure of the nanosized supramolecular SmIII complex with macrocyclic cavitand cucurbituril {[Sm(H2O)4]2(C36H36N24O12)3}Br6·44H2O
作者： D. G. Samsonenko , O. A. Gerasko , J. Lipkowski , A. V. Virovets , V. P. Fedin
关键词: Supramolecular chemistry 、 Chemistry 、 Crystal structure 、 Crystallography 、 Crystal 、 Cavitand 、 Cucurbituril 、 Samarium 、 Molecule
摘要: The supramolecular compound {[Sm(H2O)4]2(Cuc)3}Br6·44H2O (Cuc = C36H36N24O12) was synthesized. Its crystal and molecular structure established by X-ray diffraction analysis. binuclear complex cation {(Cuc)[Sm(H2O)4](Cuc)[Sm(H2O)4](Cuc)}6+ built from the alternating cucurbituril molecules (C36H36N24O12) [Sm(H2O)4]3+ aqua ions is a triple-decker nanosized (33 A) sandwich.
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sci-hub.se 参考文章(4)
Jungseok Heo, Jaheon Kim, Dongmok Whang, Kimoon Kim, Columnar one-dimensional coordination polymer formed with a metal ion and a host–guest complex as building blocks: potassium ion complexed cucurbituril Inorganica Chimica Acta. ,vol. 297, pp. 307- 312 ,(2000) , 10.1016/S0020-1693(99)00318-7
Jungseok Heo, Soo-Young Kim, Dongmok Whang, Kimoon Kim, Shape-Induced, Hexagonal, Open Frameworks: Rubidium Ion Complexed Cucurbituril Angewandte Chemie International Edition. ,vol. 38, pp. 641- 643 ,(1999) , 10.1002/(SICI)1521-3773(19990301)38:5<641::AID-ANIE641>3.0.CO;2-O
You-Moon Jeon, Jaheon Kim, Dongmok Whang, Kimoon Kim, Molecular Container Assembly Capable of Controlling Binding and Release of Its Guest Molecules: Reversible Encapsulation of Organic Molecules in Sodium Ion Complexed Cucurbituril Journal of the American Chemical Society. ,vol. 118, pp. 9790- 9791 ,(1996) , 10.1021/JA962071X
Dongmok Whang, Jungseok Heo, Joo Hyun Park, Kimoon Kim, A Molecular Bowl with Metal Ion as Bottom: Reversible Inclusion of Organic Molecules in Cesium Ion Complexed Cucurbituril Angewandte Chemie. ,vol. 37, pp. 78- 80 ,(1998) , 10.1002/(SICI)1521-3773(19980202)37:1/2<78::AID-ANIE78>3.0.CO;2-9