Chromium Compounds without CO or Isocyanides
作者： M.J. Carney , K.M. Smith
DOI: 10.1016/B978-0-12-409547-2.03885-3
关键词: Cyclopentadienyl complex 、 Organic chemistry 、 Chromium 、 Reactivity (chemistry) 、 Chromium Compounds 、 Alkyl 、 Aryl 、 Organic synthesis 、 Denticity 、 Chemistry 、 Polymer chemistry
摘要: This chapter reviews the synthesis, structure, and reactivity of organochromium compounds, excluding those containing carbonyl or isocyanide ligands, for period covering 1993–2004. Specifically, covers complexes wherein carbon ligands are primarily σ-donating alkyl aryl groups, followed by large family compounds supported π-donating (e.g., η 3 -allyl, 5 -cyclopentadienyl (Cp), 6 -arene). In addition, ligated imido nitrido functionalities summarized as oxygen, nitrogen, phosphorus, sulfur atoms; these latter often contain multiple donors bind in a multidentate fashion. The synthesis discrete heterogeneous is also reviewed, which synopsis theoretical work on chromium model systems related to olefin polymerization. Finally, selected organometallic involved oxidation chemistry organic briefly outlined.
sci-hub.se 参考文章(544)
Roy L. Beddoes, Mark S. Elwell, Frank E. Mabbs, Eric J. L. McInnes, Andrew Roberts, M. Fahad Sarwar, Mark W. Whiteley, Synthesis, redox chemistry and EPR spectroscopy of the mixed-sandwich complexes (η-arene)(η-cycloheptatrienyl)metal(z+) (M = Cr or Mo; z = 1 or 2): crystal structures of the redox pair [Cr(η-C6H5Me)(η-C7H6C6H4Me-4)][PF6]n (n = 1 or 2) Journal of The Chemical Society-dalton Transactions. pp. 4669- 4676 ,(2000) , 10.1039/B007830L
Jeffrey W. Freeman, Noel C. Hallinan, Atta M. Arif, Robert W. Gedridge, Richard D. Ernst, Fred Basolo, Syntheses, characterization, and structural and kinetic studies of half-open chromocenes and their ligand adducts Journal of the American Chemical Society. ,vol. 113, pp. 6509- 6520 ,(1991) , 10.1021/JA00017A023
Christoph Janiak, Jér??me Silvestre, Klaus H. Theopold, Metal-Metal Bonding in Paramagnetic Chromium(III) Complexes – An MO-Theoretical Case Study Chemische Berichte. ,vol. 126, pp. 631- 643 ,(1993) , 10.1002/CBER.19931260313
John E. McGrady, Periodic trends in metal–metal bonding in cubane clusters, (C5H5)4M4E4 [M = Cr, Mo, E = O, S] Journal of The Chemical Society-dalton Transactions. pp. 1393- 1400 ,(1999) , 10.1039/A900660E
Jayne C. Doherty, Katherine H. D. Ballem, Brian O. Patrick, Kevin M. Smith, Synthesis and reactivity of chromium cyclopentadienyl β-diketiminato compounds Organometallics. ,vol. 23, pp. 1487- 1489 ,(2004) , 10.1021/OM034065X
Peter Legzdins, Michael J. Shaw, Alkyl-for-Iodide Metathesis Initiated by Dissociation of the Phosphine Ligand from CpCr(NO)(PPh3)I Journal of the American Chemical Society. ,vol. 116, pp. 7700- 7705 ,(1994) , 10.1021/JA00096A029
Claire N. Temple, Sandro Gambarotta, Ilia Korobkov, Robbert Duchateau, New insight into the role of the metal oxidation state in controlling the selectivity of the Cr-(SNS) ethylene trimerization catalyst Organometallics. ,vol. 26, pp. 4598- 4603 ,(2007) , 10.1021/OM700452U
P.J. Ellis, R.W. Joyner, T. Maschmeyer, A.F. Masters, D.A. Niles, A.K. Smith, An EXAFS investigation of chromocene on silica using empirical, semi-empirical and ab initio methods Journal of Molecular Catalysis A: Chemical. ,vol. 111, pp. 297- 305 ,(1996) , 10.1016/1381-1169(96)00012-X
M. Schnellbach, F.H. Köhler, J. Blümel, The Union Carbide catalyst (Cp2Cr + SiO2), studied by solid-state NMR Journal of Organometallic Chemistry. ,vol. 520, pp. 227- 230 ,(1996) , 10.1016/0022-328X(96)06295-X
Ann R. Hermes, Robert J. Morris, Gregory S. Girolami, Twelve-electron organochromium species: synthesis and characterization of high-spin square-planar chromium(II) alkyls and aryls Organometallics. ,vol. 7, pp. 2372- 2379 ,(1988) , 10.1021/OM00101A018