Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes
作者： Paul D. Beer , Oldrich Kocian , Roger J. Mortimer
DOI: 10.1039/DT9900003283
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摘要: The syntheses and electrochemical properties of new mono- di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. corresponding ruthenium(II) complexes have been prepared one complex, [RuL4(bipy)2][PF6]2[L4= 4,4′-bis(ferrocenylvinyl)-2,2′-bipyridine], undergoes polymerisation to produce an electrochromic polymer film.
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