Effective acid-catalyzed transesterification for biodiesel production.

作者: Xiaoling Miao , Rongxiu Li , Hongyan Yao

DOI: 10.1016/J.ENCONMAN.2009.06.021

关键词:

摘要: High effective acidic transesterification catalyzed by trifluoroacetic acid for biodiesel production was studied in the present research. The results showed that oil could be converted to directly one-step catalyze process without extreme temperature and pressure conditions. optimum combination 2.0 M catalyst concentration with 20:1 ratio of methanol at 120 °C. It reduced product specific gravity from an initial value 0.965 a 0.878 about 5 h reaction time, methyl ester content reached as high 98.4%. procedure represents simple mild method short time conversion rate, which would offer potential industrial process.

参考文章(24)
G Antolın, FV Tinaut, Y Briceno, V Castano, C Perez, AI Ramırez, None, Optimisation of biodiesel production by sunflower oil transesterification Bioresource Technology. ,vol. 83, pp. 111- 114 ,(2002) , 10.1016/S0960-8524(01)00200-0
Satoshi Furuta, Hiromi Matsuhashi, Kazushi Arata, Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure Catalysis Communications. ,vol. 5, pp. 721- 723 ,(2004) , 10.1016/J.CATCOM.2004.09.001
Sandra Glisic, Oscar Montoya, Aleksandar Orlovic, Dejan Skala, Vapor-liquid equilibria of triglycerides-methanol mixtures and their influence on the biodiesel synthesis under supercritical conditions of methanol Journal of The Serbian Chemical Society. ,vol. 72, pp. 13- 27 ,(2007) , 10.2298/JSC0701013G
Andrea Salis, Marcella Pinna, Maura Monduzzi, Vincenzo Solinas, Biodiesel production from triolein and short chain alcohols through biocatalysis. Journal of Biotechnology. ,vol. 119, pp. 291- 299 ,(2005) , 10.1016/J.JBIOTEC.2005.04.009
Alok Kumar Tiwari, Akhilesh Kumar, Hifjur Raheman, Biodiesel production from jatropha oil (Jatropha curcas) with high free fatty acids: An optimized process Biomass & Bioenergy. ,vol. 31, pp. 569- 575 ,(2007) , 10.1016/J.BIOMBIOE.2007.03.003
Funda Yagiz, Dilek Kazan, A. Nilgun Akin, Biodiesel production from waste oils by using lipase immobilized on hydrotalcite and zeolites Chemical Engineering Journal. ,vol. 134, pp. 262- 267 ,(2007) , 10.1016/J.CEJ.2007.03.041
Yong Wang, Shiyi Ou, Pengzhan Liu, Zhisen Zhang, Preparation of biodiesel from waste cooking oil via two-step catalyzed process. Energy Conversion and Management. ,vol. 48, pp. 184- 188 ,(2007) , 10.1016/J.ENCONMAN.2006.04.016
Yuanyuan Xu, Wei Du, Jing Zeng and Dehua Liu, Conversion of Soybean Oil to Biodiesel Fuel Using Lipozyme TL IM in a Solvent-free Medium Biocatalysis and Biotransformation. ,vol. 22, pp. 45- 48 ,(2004) , 10.1080/10242420410001661222
Siti Zullaikah, Chao-Chin Lai, Shaik Ramjan Vali, Yi-Hsu Ju, A two-step acid-catalyzed process for the production of biodiesel from rice bran oil. Bioresource Technology. ,vol. 96, pp. 1889- 1896 ,(2005) , 10.1016/J.BIORTECH.2005.01.028