Maghnite: novel inorganic reinforcement for single-step synthesis of PDMS nanocomposites with improved thermal, mechanical and textural properties

作者: Djamal Eddine Kherroub , Tarik Boulaouche

DOI: 10.1007/S11164-020-04257-X

关键词:

摘要: A simple and efficient strategy was discussed for the synthesis of polydimethylsiloxane nanocomposites, based on in situ sonochemical polymerization hexamethylcyclotrisiloxane between nanosheets Maghnite; Maghnite is a treated Algerian mineral clay that can act as catalyst an inorganic reinforcement at same time. Three types were prepared: raw, sodium organophilic Maghnite. The nanocomposites carried out type showed greatest interlayer spacing, by varying its content weight. structure obtained materials identified FTIR-ATR 1H MAS NMR spectroscopies. Moreover, dispersion state particles examined XRD, TEM SEM. TGA has been used to study thermal properties. evaluation mechanical properties evolution measuring Young’s modulus yield strength. nitrogen adsorption capacity calculated 77 K. Exfoliated composites (5% loading) have shown better enhancement results concerning morphological, thermal, capacity.

参考文章(49)
James P. Lewicki, John J. Liggat, Mogon Patel, The thermal degradation behaviour of polydimethylsiloxane/montmorillonite nanocomposites Polymer Degradation and Stability. ,vol. 94, pp. 1548- 1557 ,(2009) , 10.1016/J.POLYMDEGRADSTAB.2009.04.030
G Camino, S.M Lomakin, M Lageard, Thermal polydimethylsiloxane degradation. Part 2. The degradation mechanisms Polymer. ,vol. 43, pp. 2011- 2015 ,(2002) , 10.1016/S0032-3861(01)00785-6
Mohamed Haouas, Amine Harrane, Mohamed Belbachir, Francis Taulelle, Solid state NMR characterization of formation of poly(ϵ‐caprolactone)/maghnite nanocomposites by in situ polymerization Journal of Polymer Science Part B. ,vol. 45, pp. 3060- 3068 ,(2007) , 10.1002/POLB.21302
Djamal Eddine Kherroub, Mohammed Belbachir, Saad Lamouri, Nylon 6/clay nanocomposites prepared with Algerian modified clay (12-maghnite) Research on Chemical Intermediates. ,vol. 41, pp. 5217- 5228 ,(2015) , 10.1007/S11164-014-1623-8
Djamal Kherroub, Mohammad Belbachir, Saad Lamouri, Preparation and Characterization of Organophilic Montmorillonite (12-maghnite) Using Algerian Clay Oriental journal of chemistry. ,vol. 30, pp. 1647- 1651 ,(2014) , 10.13005/OJC/300424
Sahar Ziraki, Seyed Mojtaba Zebarjad, Mohammad Jafar Hadianfard, A study on the tensile properties of silicone rubber/polypropylene fibers/silica hybrid nanocomposites. Journal of The Mechanical Behavior of Biomedical Materials. ,vol. 57, pp. 289- 296 ,(2016) , 10.1016/J.JMBBM.2016.01.019
Oussama Boumezgane, Federica Bondioli, Sergio Bortolini, Alfredo Natali, Aldo R Boccaccini, Elena Boccardi, Massimo Messori, None, Bioactive nanocomposites for dental application obtained by reactive suspension method Nanocomposites. ,vol. 2, pp. 37- 49 ,(2016) , 10.1080/20550324.2016.1187447
Pei Huang, Han-Qiao Shi, Shao-Yun Fu, Hong-Mei Xiao, Ning Hu, Yuan-Qing Li, Greatly decreased redshift and largely enhanced refractive index of mono-dispersed ZnO-QD/silicone nanocomposites Journal of Materials Chemistry C. ,vol. 4, pp. 8663- 8669 ,(2016) , 10.1039/C6TC02047J
Djamal Eddine Kherroub, Mohammed Belbachir, Saad Lamouri, Activated bentonite (Maghnite-H+) as green catalyst for ring-opening polymerization of 1,3,5,7-tetravinyltetramethylcyclotetrasiloxane Research on Chemical Intermediates. ,vol. 43, pp. 5841- 5856 ,(2017) , 10.1007/S11164-017-2966-8
Djamal Eddine Kherroub, Mohammed Belbachir, Saad Lamouri, Karim Chikh, Cationic Ring Opening Polymerization of Octamethylcyclotetrasiloxane Using a Cost-Effective Solid Acid Catalyst (Maghnite-H + ) Iranian Journal of Science and Technology Transaction A-science. ,vol. 43, pp. 75- 83 ,(2019) , 10.1007/S40995-017-0269-Y