Magnetically processed carbon nanotube/epoxy nanocomposites: Morphology, thermal, and mechanical properties

作者: Mohamed Abdalla , Derrick Dean , Merlin Theodore , Jennifer Fielding , Elijah Nyairo

DOI: 10.1016/J.POLYMER.2009.05.059

关键词:

摘要: The processing-structure–property relationships of multiwalled carbon nanotubes (MWNTs)/epoxy nanocomposites processed with a magnetic field have been studied. Samples were prepared by dispersing the nanotube in epoxy and curing under an applied field. nanocomposite morphology was characterized Raman spectroscopy wide angle X-ray scattering, correlated thermo-mechanical properties. modulus parallel to alignment direction, as measured dynamic mechanical analysis, showed significant anisotropy, 72% increase over neat resin, 24% sample tested perpendicular direction. A modest enhancement coefficient thermal expansion (CTE) direction also observed. These enhancements achieved even though not fully aligned, determined spectroscopy. partial is attributed resin gel time that faster than orientation dynamics. Thermal conductivity results are presented.

参考文章(57)
G. Dresselhaus, M. S. Dresselhaus, Phaedon Avouris, Carbon nanotubes : synthesis, structure, properties, and applications Springer. ,(2001)
H. Garmestani, M.S. Al-Haik, K. Dahmen, R. Tannenbaum, D. Li, S.S. Sablin, M.Y. Hussaini, Polymer‐Mediated Alignment of Carbon Nanotubes under High Magnetic Fields Advanced Materials. ,vol. 15, pp. 1918- 1921 ,(2003) , 10.1002/ADMA.200304932
Xiaoyi Gong, Jun Liu, Suresh Baskaran, Roger D. Voise, James S. Young, Surfactant-assisted processing of carbon nanotube/polymer composites Chemistry of Materials. ,vol. 12, pp. 1049- 1052 ,(2000) , 10.1021/CM9906396
J. Zhu, H. Peng, F. Rodriguez-Macias, J. L. Margrave, V. N. Khabashesku, A. M. Imam, K. Lozano, E. V. Barrera, Reinforcing Epoxy Polymer Composites Through Covalent Integration of Functionalized Nanotubes Advanced Functional Materials. ,vol. 14, pp. 643- 648 ,(2004) , 10.1002/ADFM.200305162
P. M. Ajayan, L. S. Schadler, C. Giannaris, A. Rubio, Single‐Walled Carbon Nanotube–Polymer Composites: Strength and Weakness Advanced Materials. ,vol. 12, pp. 750- 753 ,(2000) , 10.1002/(SICI)1521-4095(200005)12:10<750::AID-ADMA750>3.0.CO;2-6
Erin Camponeschi, Bill Florkowski, Richard Vance, Glenn Garrett, Hamid Garmestani, Rina Tannenbaum, Uniform Directional Alignment of Single-Walled Carbon Nanotubes in Viscous Polymer Flow Langmuir. ,vol. 22, pp. 1858- 1862 ,(2006) , 10.1021/LA052714Z
X XIE, Y MAI, X ZHOU, Dispersion and alignment of carbon nanotubes in polymer matrix: A review Materials Science & Engineering R-reports. ,vol. 49, pp. 89- 112 ,(2005) , 10.1016/J.MSER.2005.04.002
Alan Kin-Tak Lau, David Hui, The revolutionary creation of new advanced materials - Carbon nanotube composites Composites Part B-engineering. ,vol. 33, pp. 263- 277 ,(2002) , 10.1016/S1359-8368(02)00012-4
Ami Eitan, Kuiyang Jiang, Doug Dukes, Rodney Andrews, Linda S. Schadler, Surface modification of multiwalled carbon nanotubes: Toward the tailoring of the interface in polymer composites Chemistry of Materials. ,vol. 15, pp. 3198- 3201 ,(2003) , 10.1021/CM020975D