Optical and FTIR studies of CuO-doped lead borate glasses and effect of gamma irradiation

作者: H.A. ElBatal , A.M. Abdelghany , I.S. Ali

DOI: 10.1016/J.JNONCRYSOL.2011.12.069

关键词:

摘要: Abstract CuO doped lead borate glasses of the composition PbO 70%–B 2 O 3 30% with varying contents were prepared. UV–visible and infrared spectroscopic studies measured before after successive gamma irradiation two different doses namely 8 Mrad. The experimental results indicate that undoped sample reveals strong UV–near visible absorption while copper samples show additional broad band due to (Cu 2 + ) ions. FT spectrum vibrational bands triangular tetrahedral groups together sharing Pb–O vibrations. CuO-doped have been found a shielding behavior towards effects progressive causing maintenance spectral curves. changes in data are discussed relation states ions structural evolution caused by change glass including CuO.

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